1. a.* For a reaction with the stoichiometry, 2 A = P, write an expression that relates the rate of disappearance of A to the of appearance of P. b. For a reaction with the stoichiometry, A + 2B = 3P, write an expression that relates the rate of disappearance of A to the rate of disappearance of B and another expression that relates the rate of disappearance of A to the rate of appearance of P. 2. a.* For a reaction with the stoichiometry, A +2B = P, a study of the initial rate of reaction revealed that the amount of time for formation of 1% of the total amount of possible product halved when the concentration of A was doubled, and doubled when the concentration of B was halved. Write a rate expression for this reaction and suggest a stepwise mechanism for the reaction.

1. a.* For a reaction with the stoichiometry, 2 A = P, write an expression that relates the rate of disappearance of A to the of appearance of P. b. For a reaction with the stoichiometry, A + 2B = 3P, write an expression that relates the rate of disappearance of A to the rate of disappearance of B and another expression that relates the rate of disappearance of A to the rate of appearance of P. 2. a.* For a reaction with the stoichiometry, A +2B = P, a study of the initial rate of reaction revealed that the amount of time for formation of 1% of the total amount of possible product halved when the concentration of A was doubled, and doubled when the concentration of B was halved. Write a rate expression for this reaction and suggest a stepwise mechanism for the reaction.

Chemistry

9th Edition

ISBN:9781133611097

Author:Steven S. Zumdahl

Publisher:Steven S. Zumdahl

Chapter12: Chemical Kinetics

Section: Chapter Questions

Problem 3RQ: One experimental procedure that can be used to determine the rate law of a reaction is the method of...

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