1. Balance the following reactions in both acidic and basic media, identify the oxidation and reduction reactions, and identify the oxidizing and reducing agents. (Chang, 2010) a. The oxidation of iodide ion I¯ by permanganate ion Mn0, in basic solution to yield molecular iodine I2 and manganese (IV) oxide Mn02. b. Fe2+ + Mn0, → Fe3+ + Mn²+ c. Sn + NO3 Sn02 + NO2
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- A 1.000 g sample containing chlorides, iodides and inert materials was treated with dilute nitric acid followed by AgNO3. A precipitate of AgCl (143.32) and AgI (234.77) was produced and weighs 0.9238 g. On heating in a current of Cl2, the AgI is converted to AgCl, and the resulting product weighs 0.7238 g. Find the percentage of a) NaI (149.89) and b) NaCl (58.44) in the sampleA scientist was tasked to extract Fe from an aqueous suspension that contains 106 g of Fe2O3. The following steps detail the transformation of Fe2O3 (aq) to elemental iron: I. Enough sulfur trioxide gas was bubbled to Fe2O3 aqueous suspension to completely yield ferric sulfate. II. Then, 5.00 M nitric acid was added to ferric sulfate yielding an aqueous solution of ferric nitrate. III. Excess magnesium powder was added to the aqueous solution of ferric nitrate precipitating the solid iron ----- a. Write the balanced chemical reaction and the type of chemical reaction for [I], [II], [III]. Do not forget to indicate the states of the reactants and products (s, l, g).(CHOICES: COMBINATION, SINGLE DISPLACEMENT, DOUBLE DISPLACEMENT) b. What is the final mass of iron? Express final answers in 3 significant figures. c. High-concentration HCl is supposed to be added at the last part of the procedure. Briefly state its purpose.Calculate the time, in minutes, needed to plate 17.697 g of metal M at 43 Amps. The molar mass of metal M is 57.915 g/mol. M6+ + 6 e– → M Recall that, C = A*s, and Faraday’s constant, F, is 96,485 C/mole of electrons.
- The chief chemist of the Brite-Metal Electroplating Co. isrequired to certify that the rinse solutions that are discharged from the company’s tin-plating process into the municipal sewer system contain no more than 10 ppm (parts per million) by mass of Sn2+. The chemist devises the following analytical procedure to determine the concentration. At regular intervals, a 100-mL (100-g) sample is withdrawn from the waste stream and acidified to pH = 1.0. A starch solution and 10 mL of 0.10 M potassium iodide are added, and a 25.0-mA current is passed through the solution between platinum electrodes. Iodine appears as a product of electrolysis at the anode when the oxidation of Sn2+ to Sn4+ is practically complete and signals its presence with the deep blue color of a complex formed with starch. What is the maximum duration of electrolysis to the appearance of the blue color that ensures that the concentration of Sn2+does not exceed 10 ppm?1.) A sodium sulfate solution was electrolyzed using inert Pt electrodes. The cathode reaction was 2H2O + H2+2OH^-. If a current of 3.0 amp was used for 30 min, what weight of H2O gas would be produced? 2.) What volume of H2 gas at STP would be produced during the passage of 30,000 Coul in the electrolysis of H2O? 3.) Give the notation for the cell that utilizes the reaction: (a) Cl2 (g)+ 2 I^-(aq) to 2 Cl^-(aq)+I2(s), (b) what is the E^o for the cell? (c) which electrode is the cathode? 4.) The standard electrode potential fornthe Fe^2+ to Fe^(3+) + e - half reaction is -0.770V. (a) Using the Nernst equation [E=E^o - (0.059/n) log [Oxid]/[Red]]. Calculate the voltage of this half cell when the [Fe^3+] is 1.0 x 10^-3 and [Fe^2+] is 1.0 x 10 ^ -1. (b) Calculate the approximate equilibrium constant (K) for the half reaction.Prepare a complete analysis procedure using KMnO4 as teh oxidant instead of K2CrO7 in the redox analysis of iron. Include sample and solution preparation, approximate weights of samples and reagents, procedure and chemical reactions. In particular, what is the purpose of the Zimmermann-Reinhardt reagent?
- Given: You weigh out exactly 0.200 g of Fe(NH4)2(SO4)2·6H2O and dissolve it in the 100.00 mL volumetric flask. You then pipette 2.00 mL of this solution into the 50.00 mL volumetric flask to prepare the stock standard tris-bipyridyl-iron(II) solution. a. Calculate the molar concentration of iron(II) in this solution in the 50.00 mL volumetric flask. (The MW of Fe(NH4)2(SO4)2·6H2O is 392.14 g/mol) (answer a given the information above)4.Why is there % error in APF cells? What could be the reason for such error? 5. By understanding the structure of crystals molecularly, what is its relation to the strength of materials? 6. Use the internet to search three (3) examples of metals which have HCP, FCC and BCC structures. Relate the structure to the characteristic properties of each metal. Please indicate the condition the given structures are observed.In order to draw Pourbaix Diagram for a metal, all possible electrochemical and chemical reactions have to be known and with the application of Nernst equation or solubility product constant, the E-pH diagram can be constructed. We have looked at the diagram for Fe. While the Pourbaix diagram of Fe is quite complex due to its two oxidation states +2 and +3, construct a simplified Pourbaix diagram for Fe considering only the following three reactions. Note: CFe+2 and CFe+3 can be taken as 10-6 M Fe ----- Fe+2 + 2e- 2Fe+2 + 3H2O ----- Fe2O3 + 6H+ + 2e- 2Fe+3 + 3H2O ----- Fe2O3 + 6H+
- Write a balanced ionic equation to represent the oxidation of iodide ion (I- ) by permanganate ion (MnO4) in basic solution to yield molecular iodine (I- ) and manganese(IV) oxide (MnO2).Below are the reduction half reactions for chemolithoautotrophic nitrification, where ammonia is a source of electrons and energy and oxygen is the terminal electron acceptor. NO2- + 6e- -> NH4+ (E0 = +0.34 volts) O2 + 4e- -> 2H2O (E0 = +0.82 volts) If you balance and combine the reactions so that 293 moles of NH4+are oxidized to NO2-, how many moles of electrons will be transferred from Nitrogen to Oxygen?Many applications of electrochemistry have been in chemical analysis.Suppose a Fe|Fe2+ concentration cell is set-up in which the [Fe2+] = 1.0 x10¯2 M in one compartment but the concentration in the othercompartment is unknown. The Ecell was measured at 0.024V when thehalf-cells were connected.(i) Without doing a numerical calculation, is the unknown more orless concentrated than the 1.0 x 10¯2 M solution? Justify youranswer