1. Calculate the potential as a function of titrant volume when 50 mL of 0.100 M Fe* is titrated with 20.0, 50.0, and 53.0 mL of 0.100M Cet. Given: Keg = 1.7 x 1014, Fe + e • Fe2"; E° = 0.767 V Ce+ + e Ce+; E° = 1.70 V [Fe2*] E = 0.767V – 0.0592 log: Fes1 [Cest] E = 1.7V - 0.0592 log- [Ce+] (n, E"+n,E") Eea red- n,+n,

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
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Chapter17: Complexation And Precipitation Reactions And Titrations
Section: Chapter Questions
Problem 17.29QAP
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1. Calculate the potential as a function of titrant volume when 50 mL of 0.100 M Fe* is titrated
with 20.0, 50.0, and 53.0 mlL of 0.100M Cet.
Given: Keg = 1.7 x 1014,
Fet + e
• Fe2; E° = 0.767 V
Ce+ +e
+ Cet; E0 = 1.70 V
[Fe2*]
E = 0.767V - 0.0592 log-
Fes1
[Ce3+1
E = 1.7V – 0.0592 log
[Ce*]
(n, E"+n,E",ea)
Eeq
n,+n,
Transcribed Image Text:1. Calculate the potential as a function of titrant volume when 50 mL of 0.100 M Fe* is titrated with 20.0, 50.0, and 53.0 mlL of 0.100M Cet. Given: Keg = 1.7 x 1014, Fet + e • Fe2; E° = 0.767 V Ce+ +e + Cet; E0 = 1.70 V [Fe2*] E = 0.767V - 0.0592 log- Fes1 [Ce3+1 E = 1.7V – 0.0592 log [Ce*] (n, E"+n,E",ea) Eeq n,+n,
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