1. Determine the relationship between the two structures below. Circle your answer. H. Br H H CH3 H (CH3)3C-H CI-CI AH°-400 kJ/mol AH° 243 kJ/mol Br + (a) Enantiomers (b) Diastereomers 2. The bond dissociation energies for the relevant bonds are given below. Calculate the overall AHⓇ for the reaction. Place your answer in the box without units. (c) Identical (d) Constitutional isomers → (CH3)3C-CI + H-CI AH°-349 kJ/mol AH-432 kJ/mol kJ/mol

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter12: Chirality
Section: Chapter Questions
Problem 18E
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1. Determine the relationship between the two structures below. Circle your answer.
H
Br
H
H
CH3
H
H
H
+
(CH3)3C-H
CI-CI
AH⁰=400 kJ/mol AH°=243 kJ/mol
Br
(a) Enantiomers
(b) Diastereomers
2. The bond dissociation energies for the relevant bonds are given below. Calculate the overall AH° for the
reaction. Place your answer in the box without units.
(CH3)3C-CI
AH° 349 kJ/mol
☐ (c) Identical
(d) Constitutional isomers
+ H-CI
AH°=432 kJ/mol
kJ/mol
Transcribed Image Text:1. Determine the relationship between the two structures below. Circle your answer. H Br H H CH3 H H H + (CH3)3C-H CI-CI AH⁰=400 kJ/mol AH°=243 kJ/mol Br (a) Enantiomers (b) Diastereomers 2. The bond dissociation energies for the relevant bonds are given below. Calculate the overall AH° for the reaction. Place your answer in the box without units. (CH3)3C-CI AH° 349 kJ/mol ☐ (c) Identical (d) Constitutional isomers + H-CI AH°=432 kJ/mol kJ/mol
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