1. K₂[Co(dme)(bpy)(NCS)CI₂] i. ii. iii. Coordination compound Determine the oxidation state of central metal and coordination number of the complex. Write down the quantum number of the outmost orbital of the central metal. Determine the magnetic behavior of the central metal.
1. K₂[Co(dme)(bpy)(NCS)CI₂] i. ii. iii. Coordination compound Determine the oxidation state of central metal and coordination number of the complex. Write down the quantum number of the outmost orbital of the central metal. Determine the magnetic behavior of the central metal.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter21: Transition Metals And Coordination Chemistry
Section: Chapter Questions
Problem 108IP: a. In the absorption spectrum of the complex ion Cr(NCS)63, there is a band corresponding to the...
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![1.
K₂[Co(dme)(bpy) (NCS)Cl₂]
i.
ii.
iii.
iv.
V.
vi.
vii.
viii.
ix.
X.
Coordination compound
Determine the oxidation state
of central metal and
coordination number of the
complex.
Write down the quantum
number of the outmost orbital
of the central metal.
Determine the magnetic
behavior of the central metal.
Name the compound above.
and draw a structure of the
complexes.
Highlight the donor atom and
give the likely modes of
bonding of the ligand dme
(e.g: monodentate)
If dme ligand has been
replaced by anion ligand acac
and bpy ligand has been
replaced by any anionic
monodentate ligand, name
and draw a structure of a new
coordination compound.
Give an example of a ligand
that has the same modes of
bonding with dme and bpy.
Determine whether the
complex follows the
18-electron rule or not.
Sketch the structure of the
two linkage isomers of the
complex
K₂[Co(dme)(bpy) (NCS)CI₂].
Does this complex
(K. [Co(dme)(bpy) (NCS)CI,])
have the potential to form
geometrical isomers? if so,
sketch the isomer involved.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fafd5b681-2abb-48eb-ab13-bebde239e86b%2F5fb53371-fa8f-45d1-9fdf-0343091b4c09%2Fsbj68k8_processed.jpeg&w=3840&q=75)
Transcribed Image Text:1.
K₂[Co(dme)(bpy) (NCS)Cl₂]
i.
ii.
iii.
iv.
V.
vi.
vii.
viii.
ix.
X.
Coordination compound
Determine the oxidation state
of central metal and
coordination number of the
complex.
Write down the quantum
number of the outmost orbital
of the central metal.
Determine the magnetic
behavior of the central metal.
Name the compound above.
and draw a structure of the
complexes.
Highlight the donor atom and
give the likely modes of
bonding of the ligand dme
(e.g: monodentate)
If dme ligand has been
replaced by anion ligand acac
and bpy ligand has been
replaced by any anionic
monodentate ligand, name
and draw a structure of a new
coordination compound.
Give an example of a ligand
that has the same modes of
bonding with dme and bpy.
Determine whether the
complex follows the
18-electron rule or not.
Sketch the structure of the
two linkage isomers of the
complex
K₂[Co(dme)(bpy) (NCS)CI₂].
Does this complex
(K. [Co(dme)(bpy) (NCS)CI,])
have the potential to form
geometrical isomers? if so,
sketch the isomer involved.
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