1. Methanol is an organic solvent and is also used as a fuel in some automobile engines, From the following data, calculate the standard enthalpy of formation of methanol: 2CH,OH() +30,(g) 2CO,(g) + 4H,O(1) AH°(CO2.g) =-393.5 kJ/mol and AH, (H;O,1) =-285.8 kJ/mol AH"rxn =-1452.8 kJ/mol AHixn - C2AHCCO)+4AHCHL - (20HCO4)-30t) AHeen - [2 (-398-5)+ 4G-285.8)) -26 McHpH 33 474 - 4528 - [-1930-2 kjl ma)- 2AHCH,OH 2AHCHsoH

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Chapter7: Chemical Energy
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1. Methanol is an organic solvent and is also used as a fuel in some automobile engines.
From the following data, calculate the standard enthalpy of formation of methanol:
2CH,OH) + 30:(g) 2CO,(g) + 4H;0(1)
AH°(CO2.g) =-393.5 kJ/mol and AH° (H;O.1) =-285.8 kJ/mol
AH"rxn =-1452.8 kJ/mol
AHen = [2 (-398-5) + 4-285.8 2A MCH
- 4528
[-1930-2 kjl na)-2AHCH,OH-2AHCH3OH
%3D
2. In a calorimeter, 1.00L of 1.00 M Ba(NO,); at 25°C and 1.00L of 1.00 M Na,SO, at
25°C are mixed. The temperature increased to 28.1°C and white BaSO, is formed
according to the following reaction:
Ba"(aq) + So, (aq) - BaSO(s)
a) Is the above reaction exothermic or endothermic?
Ba(NO3)2 +Naz Soua Ba soy + NaNOg
exotnermic
b) Assuming that the heat capacity of the calorimeter is negligible, that the specific
heat of the solution is 4.184 J°CI
1.0 g/mL, calculate AH per mole of BaSO, formed.
Formula: Ba (NO3)2+Nao, SOu >2 NaNO3 +Bas ou
g" and that the density of the final solution is
9- 20009) (4184 Fa) (28-1-25t).25940.833 The neat of
given of as
=25940-85
The amountof
neat energY
requireda -25940-85
- 200m x 09 - 20009
3. A 5.368 g sample of NH NO, is added to 40.0 mL of water in calorimeter
at 23.5°C and the final temperature of the solution is 21.4 °C.
Calculate the heat of solution of ammonium nitrate in kJ/mol
[specific heat of water = 4.18J/g. "C; density of water = 1.00 g/ml;
heat capacity of the calorimeter = 650. J/°C]
M-Vad - 40x1-409
9 Calori -Coue DT
650x (21.4 -23.5)-1365]
4-grxn- 9water+ acaloie
qwater -ms DE
9 water - 4o9 x 4.18 x .u-23-5)
awater- -351.125
9anE 9 wakert 9 calone
aan--3511251365
arxn- (716.120
AH: 76.3
Transcribed Image Text:1. Methanol is an organic solvent and is also used as a fuel in some automobile engines. From the following data, calculate the standard enthalpy of formation of methanol: 2CH,OH) + 30:(g) 2CO,(g) + 4H;0(1) AH°(CO2.g) =-393.5 kJ/mol and AH° (H;O.1) =-285.8 kJ/mol AH"rxn =-1452.8 kJ/mol AHen = [2 (-398-5) + 4-285.8 2A MCH - 4528 [-1930-2 kjl na)-2AHCH,OH-2AHCH3OH %3D 2. In a calorimeter, 1.00L of 1.00 M Ba(NO,); at 25°C and 1.00L of 1.00 M Na,SO, at 25°C are mixed. The temperature increased to 28.1°C and white BaSO, is formed according to the following reaction: Ba"(aq) + So, (aq) - BaSO(s) a) Is the above reaction exothermic or endothermic? Ba(NO3)2 +Naz Soua Ba soy + NaNOg exotnermic b) Assuming that the heat capacity of the calorimeter is negligible, that the specific heat of the solution is 4.184 J°CI 1.0 g/mL, calculate AH per mole of BaSO, formed. Formula: Ba (NO3)2+Nao, SOu >2 NaNO3 +Bas ou g" and that the density of the final solution is 9- 20009) (4184 Fa) (28-1-25t).25940.833 The neat of given of as =25940-85 The amountof neat energY requireda -25940-85 - 200m x 09 - 20009 3. A 5.368 g sample of NH NO, is added to 40.0 mL of water in calorimeter at 23.5°C and the final temperature of the solution is 21.4 °C. Calculate the heat of solution of ammonium nitrate in kJ/mol [specific heat of water = 4.18J/g. "C; density of water = 1.00 g/ml; heat capacity of the calorimeter = 650. J/°C] M-Vad - 40x1-409 9 Calori -Coue DT 650x (21.4 -23.5)-1365] 4-grxn- 9water+ acaloie qwater -ms DE 9 water - 4o9 x 4.18 x .u-23-5) awater- -351.125 9anE 9 wakert 9 calone aan--3511251365 arxn- (716.120 AH: 76.3
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