1. MF CH₂NO 100 Relative Intensity 80- 95 T 20- 0-m 25 50 tumum 75 100 125

Fundamentals Of Analytical Chemistry
9th Edition
ISBN:9781285640686
Author:Skoog
Publisher:Skoog
Chapter27: Molecular Fluorescence Spectroscopy
Section: Chapter Questions
Problem 27.7QAP
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Show complete details.

A) Identify the structure of the important fragments. 

B) Show the arrow pushing mechanism to form the significant fragments. 

C) Suggest possible structure based on MS and IR data.

 

1. MF C₂H₂NO
100
80
Relative Intensity
60
40
20
0-tabletkrobatum
25
50
75
m/z
100
125
15.0
18.0
27.0
28.0
30.0
38.0
39.0
50.0
51.0
52.0
53.5
58.0
74.0
75.0
76.0
77.0
78.0
105.0
106.0
134.0
135.0
136.0
1.5
1.4
1.9
2.4
1.8
1.5
2.3
10.9
31.4
2.8
1.1
3.9
3.5
2.7
4.5
87.2
7.9
100.0
8.5
32.4
38.4
3.6
Transcribed Image Text:1. MF C₂H₂NO 100 80 Relative Intensity 60 40 20 0-tabletkrobatum 25 50 75 m/z 100 125 15.0 18.0 27.0 28.0 30.0 38.0 39.0 50.0 51.0 52.0 53.5 58.0 74.0 75.0 76.0 77.0 78.0 105.0 106.0 134.0 135.0 136.0 1.5 1.4 1.9 2.4 1.8 1.5 2.3 10.9 31.4 2.8 1.1 3.9 3.5 2.7 4.5 87.2 7.9 100.0 8.5 32.4 38.4 3.6
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