5   0.0030   0.0015   0.0005   6   0.0030   0.0057   0.0089   7   0.0086   0.0057   0.0089 Show the Calculations of Qc and Kc for Exp. 5-7

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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5

 

0.0030

 

0.0015

 

0.0005

 

6

 

0.0030

 

0.0057

 

0.0089

 

7

 

0.0086

 

0.0057

 

0.0089

Show the Calculations of Qc and Kc for Exp. 5-7

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tpermehe touune
Demiy 200-Gener Oemiry
Dept of hi Soencm&Engneering
wibur Wrght Coteg
Show the Cakulations of aand K. for t. 57
Caletiona
ICon of
Caktaion ofa
Transcribed Image Text:tpermehe touune Demiy 200-Gener Oemiry Dept of hi Soencm&Engneering wibur Wrght Coteg Show the Cakulations of aand K. for t. 57 Caletiona ICon of Caktaion ofa
Wilbur Wright College
REPORT
Table 1: Initial & Equilibrium Concentrations
[Fe") (M)
[SCN] (M)
(FESCN) (M)
(Fe"l (M)
5.58 10 M
(SCN J (M)
(FESCN (M)
4.42 *10 M
Exp.
5.58 *10 M
1
0.010
0.010
3.38 *10 M
3.38 * 10 M
1.62 10 M
2
0.0050
0.0050
4.55 10 M
4.55 10 M
2.95 10 M
3
0.0050
0.0050
0.0025
4.99* 10 M
8.49 10 M
6.01 10 M
4
0.0025
0.0060
0.0085
2.9* 20 M
1.41 10 M
5.85 10 M
5
0.0030
0.0015
0.0005
6
0.0030
0.0057
0.0089
5.50* 10 M
8.20* 10 M
6.40* 10 M
9.22* 10 M
6.32* 10 M
8.28* 10 M
0.0086
0.0057
0.0089
Transcribed Image Text:Wilbur Wright College REPORT Table 1: Initial & Equilibrium Concentrations [Fe") (M) [SCN] (M) (FESCN) (M) (Fe"l (M) 5.58 10 M (SCN J (M) (FESCN (M) 4.42 *10 M Exp. 5.58 *10 M 1 0.010 0.010 3.38 *10 M 3.38 * 10 M 1.62 10 M 2 0.0050 0.0050 4.55 10 M 4.55 10 M 2.95 10 M 3 0.0050 0.0050 0.0025 4.99* 10 M 8.49 10 M 6.01 10 M 4 0.0025 0.0060 0.0085 2.9* 20 M 1.41 10 M 5.85 10 M 5 0.0030 0.0015 0.0005 6 0.0030 0.0057 0.0089 5.50* 10 M 8.20* 10 M 6.40* 10 M 9.22* 10 M 6.32* 10 M 8.28* 10 M 0.0086 0.0057 0.0089
Expert Solution
Step 1

The equilibrium reaction between the Fe3+ ion and SCN- ion to given an iron thiocyanate complex can be written as follows.

Fe2+(aq)+SCN-FeSCN-(aq)

Qc is the reaction quotient for the given reaction, which can be defined as the ratio of the molar concentration of product to that of the molar concentration of the reactant at that instant of time raised that are raised to their respective stoichiometric coefficient.

So, for this the reaction quotient Qc can be written as the following expression.

Qc=[FeSCN-]Fe2+SCN-

The equilibrium constant Kc is similar to the reaction quotient but differs in terms of the concentrations that are used to find the ratio. In equilibrium constant, the equilibrium concentration of the products and reactants are used. For equilibrium concentration, subscript of 'eq' can be used to differentiate the concentration temp used for the expression of equilibrium constant.

Kc=[FeSCN-]eqFe2+eq·SCN-eq

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