1. Predict and draw the structure of the product of the reaction of the following substrates with the given reducing agent. For c) indicate which components reacted. a) hexanal with NaBH4 b) 2-hexanone with LiAlH4 c) 2-hexanone mixed with hexanoic acid with i) NaBH4 ii) LiAlH4

1. Predict and draw the structure of the product of the reaction of the following substrates with the given reducing agent. For c) indicate which components reacted. a) hexanal with NaBH4 b) 2-hexanone with LiAlH4 c) 2-hexanone mixed with hexanoic acid with i) NaBH4 ii) LiAlH4

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter23: Addition To A Carbonyl

Section: Chapter Questions

Problem 42CTQ

See similar textbooks

Related questions

Q: Draw the major organic product(s) of the following reaction. 1 eq. NaNH2, NH3()) H-CEC-H CH3-1

A: Answer:NaNH2 in liquid ammonia acts as a strong base, and hydrogen at "sp" hybridised carbon is…

Q: What is the percent yield for the reaction: PCI3(g) + CI2(g) -> PCl5(g). if 119.3g of PCI5 (FM =…

A: A balanced chemical equation contain equal number of atoms of each elements on both sides of the…

Q: Chapter 5 Question 21 If possible, draw the structure of the enantiomer of the molecule shown below.…

A: Answer:Enantiomers are the stereoisomers that are mirror images of each other and these mirror…

Q: A pka = 8 CHO B pka = 5 Explain why A is more basic than B? (Try to draw the p orbital of denoted…

A: The basicity of the given compounds depends on the availability of line pair on the nitrogen.

Q: Cyclohexane structures can have two chair conformations. Draw the alternate conformation of the…

A: The conformational isomers are formed by the rotation of a carbon-carbon single bond in a…

Q: Somers & Stereolsomers Сонно 1-bromopentane C5H₁, CI

A: Isomers are the compounds having similar molecular formula but different structural formulas.…

Q: Draw the products of each SN1 reaction and indicate the stereochemistry when necessary. Br CH₂CH₂…

A: The unimolecular nucleophilic substitution reaction is known as SN1 reaction. It is a two step…

Q: Choose the most stable, lowest energy alkene. 다 ㅂ

A: Given are organic compounds.Given compounds has same molecular formula but different structural…

Q: Question 5: The mass of a calcium-40 atom is 39.9626 amu The mass of a proton, neutron, and electron…

A: Mass of Ca-40 = M = 39.9626 u -------------------------------------------

Q: In the Periodic Table below, shade all the elements for which the neutral atom has an outer electron…

A: Electronic configuration can be define as the arrangement of electrons symmetrically into various…

Q: Which of the following features in a Lineweaver-Burk plot is altered by a competitive inhibitor in…

A: The mechanism of an enzyme-catalyzed reaction was initially proposed by Michaelis and Menten and is…

Q: In the below Lewis structure, how many electrons are located in cova bonds? :O: F-CEC-N C=O -H

A: Given is lewis structure of organic compound. Covalent bond is bond that formed by mutual sharing of…

Q: This is the correct elimination product. True False CI Me H I NaOMe Me H

A: Given reaction is elimination reaction.Here, alkyl chloride is converted into alkene using base…

Q: Could someone please help with this practice problem? Provide a step-by-step mechanism for the…

A: This is the haloacid addition reaction of alkene.This reaction preceed through carbocation…

Q: What is the temperature of 3.95 gg of helium gas at a pressure of 1.70 atmatm and a volume of 15.1 L…

A: The mass of helium gas = 3.95 gThe pressure of the gas = 1.70 atm The volume of the gas = 15.1 LThe…

Q: Br 12.

Q: Select the prod o ردد C

A: This is an example of the pericyclic reaction. This reaction follows a concerted mechanism involving…

Q: Draw all stereoisomers CI CI CI CI

Q: What is the product of the reaction sequence shown? CI AICI3 2. I2, CuCh Product?

A: Given a benzene, isobutyl chloride, Lewis acids (AlCl3 and CuCl2 ) and I2 .Find out the product

Q: A gold cube is 150.00 mm long, 10.00 cm wide, and 0.95 m thick. If gold has a density of 19.3g/cm^3,…

A: The density of any substance is defined as the ratio of its mass to the volume of the substance.

Q: Draw the major organic product(s) of the following reactions including stereochemistry when it is…

A: Alkynes are organic compounds that have triple bond so they have excess electron density.They behave…

Q: 4.- Determine the structural relationship between the compounds in each of the pairs that follow.…

A: Since you have asked a question with multiple sub-parts, we will solve the first three parts for…

Q: Draw Lewis structures for SeF4 and SeF6 and include all electron lone pairs. Is the octet rule…

A: Lewis’s bonding theory is based on the octet rule. The Lewis structure is a simplified…

Q: Which one is the major organic product obtained from the following reaction? 1. NaOCH₂CH3 CH3CH₂OH…

A: First step of this reaction involve abstraction of most acidic hydrogen from active methylene…

Q: Determine the molarity of a solution formed by dissolving 0.455 moles of NaCl in enough water to…

A: The moles of NaCl = 0.455 mol The volume of solution = 294 mL = 0.294 L…

Q: Draw the structure (4S,5S,7S)-7- bromo-5-sec-butyl-4-ethyl-3,3- dimethylnonane.

A: Given is organic compound.The name of given compound…

Q: Draw the conjugate acid for the following base (lone pairs do not have to be drawn):

A: In the Bronsted–Lowry definition of acids and bases, a conjugate acid–base pair consists of two…

Q: Provide the correct IUPAC name for the skeletal (line-bond) structure shown here. Stereochemistry is…

A: Given:Give the correct IUPAC name for this structure.The IUPAC nomenclature, is a set of…

Q: correct IUPAC name for the compound sho H3C. CI CH3

A: IUPAC name of the given compound = ?

Q: What mass of precipitate (in g) is formed when 20.5 mL of 0.500 M Cu(NO3) 2 reacts with 39.5 mL of…

A: Answer:Limiting reagent is the reactant that is exhausted first in the chemical reaction and decides…

Q: Classify the following reaction and balance the equation by entering the smallest possible integer…

A: Type of reaction = ?Balanced reaction = ?

Q: A hypothetical compound has a molar mass of 368.62 g/mol. How many moles are there in 114.6 grams of…

A: The molar mass of the compound = 368.62 g/molThe mass of compound = 114.6 gramsThe moles of compound…

Q: It takes 489 kJ to remove one mole of electrons from the atoms at the surface of a solid metal. What…

Q: Are the following chiral, achiral, or mese

Q: A Lab Data Verify your volume measurement Verify your calculation Incorrect decimal places, refer to…

A: The question is based on the titration. We are titrating a weak acid with a strong base. We need to…

Q: (i) E HO OH OH acetone H*, Heat 1. NaBH4 H 2. H, Heat 2.

Q: Decide whether each chemical reaction in the table below is an oxidation-reduction ("redox")…

A: In a redox reaction, oxidation and reduction occur simultaneously.

Q: tab 6:36 PM Mon Oct 9 What quantity in moles of precipitate will be formed when 78.3 mL of 0.300 M…

A: The question is based on the concept of reaction stoichiometry.We need to calculate quantity of…

Q: reactions? by Ni f. CH₂ CH₂ C 2. H₂0 NH₂ CeHsLi 1. BF₂/THF + CH₂CH₂CH₂Br

A: Question D is example of fridel craft reaction and question F is example of nucleophilic…

Q: The solubility product for an insoluble salt with the formula M2X3 is written as __________, where s…

A: Solubility product of an electrolyte is defined as a product of the molar concentration of all its…

Q: Which molecule experiences the most angle strain?

A: The bond angle of the tetrahedral carbon atom (sp3 hybridized carbon atom) is 109.5o. In the…

Q: An unknown compound has an emperical formula of C2H3O and a molecular mass of 86 amu. 1) draw a…

A: The objective of the question is to-Draw the structure for the compound that contains alcohol,…

Q: Have this multistep condensation reaction series for practice -- any assistance in understanding the…

A: The question is based on organic reactions. We need to identify the product and explain its…

Q: ii. i. iii. iv. V. a. Provide the correct IUPAC names for the following compounds. H₂N H₂C H3C H₂C…

A: -Select the parent chain with the longest possible continuous carbon chain with a maximum number of…

Q: CH3OH(g) ⇒ CO(g) + 2 H2(g) If the value of Kp at 227 °C is 1.95 × 10-³, what is Kc at this…

A: Given reaction is, CH3OH(g) ⇒ CO(g) + 2 H2(g)Kp at 227 °C is 1.95 × 10-3T = temperature in K = T in…

Q: We don't see the answer written with a photo or pen, give the answer using the tool

A: Actetals are derived from aldehydes or ketone. It contains two alkoxy groups bonded to central…

Q: At a certain temperature, the equilibrium constant K for the following reaction is 1.3: NO₂(g) +…

A: Answer:Given reaction:equilibrium constant expression for the above reaction is:Here value of K is…

Q: Ranitidine sulfur-containing side chain has substituted guanidine with pka of 2.7 for the secondary…

A: Ionization suggests the existence of a compound as an ionic species or ions. That is, a compound…

Q: Wine goes bad soon after opening because the ethanol (CH³CH₂OH) dissolved in it reacts with oxygen…

A: moles of acetic acid (CH3COOH) produced = 0.090 molmoles of ethanol (CH3CH2OH) needed = ?

Q: Gaseous ammonia chemically reacts with oxygen (O₂) gas to produce nitrogen monoxide gas and water…

A: The balanced equation involved:

Concept explainers

Aromatic Compounds

Aromatic organic compound or aromatic system is an important class of hydrocarbons under the branch of organic chemistry. Aromatic compounds are also called arenas. The definition of aromatic organic compounds can be stated as a class of organic compounds with a planar cyclic ring of atoms bonded through alternated single and double bonds. Due to these alternating bonds, a peculiar feature termed as ‘resonance’, that is, delocalization of pi electrons or the electrons is shared within the atoms of the ring which are present in the aromatic compounds. The word ‘aromatic’ includes a Greek word ‘aroma’ which means smell, indicating that they were named as such due to the sweet odor they produce. Many well-known flavors such as vanilla, cinnamon, and few scents from flowers are extracted from aromatic compounds. Benzene with chemical formula C6H6 is a very common aromatic compound that contains six atoms of carbon held in the cyclic ring of alternate double bonds. It is also to be noted that not all aromatic compounds contain benzene ring. This can be explained by Huckel’s rule.

Question

100%

1. Predict and draw the structure of the product of the reaction of the following substrates with the given reducing agent. For c) indicate which components reacted.

a) hexanal with NaBH4

b) 2-hexanone with LiAlH4

c) 2-hexanone mixed with hexanoic acid with

i) NaBH4

ii) LiAlH4

Expert Solution

This question has been solved!

Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.

This is a popular solution!

SEE SOLUTION Check out a sample Q&A here

Step 1: Determine the products of the given reactions:

VIEW

Step 2: a) The reacton of hexanal with NaBH4:

VIEW

Step 3: b. The reaction 2-hexanone with LiAlH4:

VIEW

Step 4: c. (i) The reaction with NaBH4:

VIEW

Step 5: (ii) The reaction with LiALH4:

VIEW

Solution

VIEW

Trending now

This is a popular solution!

Step by step

Solved in 6 steps with 5 images

SEE SOLUTION Check out a sample Q&A here

Knowledge Booster

Learn more about

Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.

Similar questions

Propose a mechanism for the acid-catalyzed hydration of propene. Remember that a mechanism must include curved arrows to show movement of electrons, as well as all intermediates.
How to get the molecule given below by getting out of bromobenzene and using the reagents you want? You synthesize? Show it.
Choose the best reagents from the list provided below for carrying out the following conversion. Match the reagent with the step number. HCl (aq), Zn(Hg) KMnO4, H3O+ CH3Cl, AlCl3 HNO3, H2SO4 Cl2, FeCl3 fuming sulfuric acid
Wittig reactions with the following -chloroethers can be used for the synthesis of aldehydes and ketones. (a) Draw the structure of the triphenylphosphonium salt and Wittig reagent formed from each chloroether. (b) Draw the structural formula of the product formed by treating each Wittig reagent with cyclopentanone. Note that the functional group is an enol ether or, alternatively, a vinyl ether. (c) Draw the structural formula of the product formed on acid-catalyzed hydrolysis of each enol ether from part (b).
(a) What reagents would be used for the conversion of alkene A into the target? (b) What reaction is involved in the conversion of alcohol B into alkene A? Suggest a reagent that might affect this transformation. (c) Give a retrosynthetic analysis showing the disconnection of B, the synthons produced that lead to the synthetic equivalents given (draw their structures).
Please give the appropriate reagents FOR 3 and 4 to complete the following synthesis. ******** Keep mind, H2/PD does NOT go into 3 and KMNO4 does NOT
Consider the reaction of the cyclopentanone derivative shown below. Draw the structure for the major product formed in this reaction. The cyclopentanone ring has been provided as a starting point.
What is reaction 1 and 2 called? Choices: A. Williamson ether synthesis, B. Reduction with Grignard reagent, C. Acidic ether cleavage, D. FC Alkylation What are the reagents for reaction 1 and 2? Choices: A. methanol in acidic medium, B. sodium hydride and bromomethane, C. methyl bromide and aluminum bromide, D. methanoyl bromide
Which or which of the statements given below is correct. I) Maleic anhydride is a carboxylic acid derivative and its reaction with water is a reduction reaction. II) Fumaric acid and maleic acid are stereoisomers of each other III) Since fumaric acid has a more stable structure than maleic acid, its boiling point is higher. A. Solo I B. I and III C. II and III D. I, II, III E. Solo III
What functional group would be present in the product (the main organic product) of a reaction between a ketone and a Grignard reagent (with an acidic workup/quench)? Be specific (primary, secondary, tertiary).
I’m having trouble find the major product could you help find the reagent that is reasonable to find the product?
1) Redraw the structure and assign E or Z configuration to each double bond in the molecule. 2) Draw the organic products obtained from the ozonolysis of the compound, using a reductive work-up with zinc/HAc.