1. Tetrahedral angles. The angles between the tetrahedral bonds of diamond are the same as the angles between the body diagonals of a cube, as in Fig. 10. Use elemen- tary vector analysis to find the value of the angle. 2. Indices of planes. Consider the planes with indices (100) and (001); the lattice is fcc, and the indices refer to the conventional cubic cell. What are the indices of these planes when referred to the primitive axes of Fig. 11? 3. Hcp structure. Show that the c/a ratio for an ideal hexagonal close-packed struc- ture is()¹/2 = 1.633. If c/a is significantly larger than this value, the crystal structure may be thought of as composed of planes of closely packed atoms, the planes being loosely stacked.

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Chapter1: Units, Trigonometry. And Vectors
Section: Chapter Questions
Problem 1CQ: Estimate the order of magnitude of the length, in meters, of each of the following; (a) a mouse, (b)...
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1. Tetrahedral angles. The angles between the tetrahedral bonds of diamond are the
same as the angles between the body diagonals of a cube, as in Fig. 10. Use elemen-
tary vector analysis to find the value of the angle.
2. Indices of planes. Consider the planes with indices (100) and (001); the lattice is
fcc, and the indices refer to the conventional cubic cell. What are the indices of
these planes when referred to the primitive axes of Fig. 11?
3. Hcp structure. Show that the c/a ratio for an ideal hexagonal close-packed struc-
ture is()¹/2 = 1.633. If c/a is significantly larger than this value, the crystal structure
may be thought of as composed of planes of closely packed atoms, the planes being
loosely stacked.
Transcribed Image Text:Problems 1. Tetrahedral angles. The angles between the tetrahedral bonds of diamond are the same as the angles between the body diagonals of a cube, as in Fig. 10. Use elemen- tary vector analysis to find the value of the angle. 2. Indices of planes. Consider the planes with indices (100) and (001); the lattice is fcc, and the indices refer to the conventional cubic cell. What are the indices of these planes when referred to the primitive axes of Fig. 11? 3. Hcp structure. Show that the c/a ratio for an ideal hexagonal close-packed struc- ture is()¹/2 = 1.633. If c/a is significantly larger than this value, the crystal structure may be thought of as composed of planes of closely packed atoms, the planes being loosely stacked.
ap
Figure 10 Primitive translation vectors of the body-
centered cubic lattice; these vectors connect the lattice
point at the origin to lattice points at the body centers.
The primitive cell is obtained on completing the rhom-
bohedron. In terms of the cube edge a, the primitive
translation vectors are
a₁ = (x + ŷ-2);
a = (-+ŷ+2) :
a = a (x -ŷ + 2).
Here &, y, 2 are the Cartesian unit vectors.
Transcribed Image Text:ap Figure 10 Primitive translation vectors of the body- centered cubic lattice; these vectors connect the lattice point at the origin to lattice points at the body centers. The primitive cell is obtained on completing the rhom- bohedron. In terms of the cube edge a, the primitive translation vectors are a₁ = (x + ŷ-2); a = (-+ŷ+2) : a = a (x -ŷ + 2). Here &, y, 2 are the Cartesian unit vectors.
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