1. The reaction of peroxydisulfate ion (S.O.") with iodide ion (1) is S,0, (aq) + 31'(aq) → 2s04 (aq) + l'3 (aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. (S:O, ] (M) (1-) (M) Initial Rate (Mis) 2.2 x 104 1.1 x 104 Experiment 1 0.080 0.034 0.080 0.017 3 0.16 0.017 2.2 x 104

Chemistry for Engineering Students
4th Edition
ISBN:9781337398909
Author:Lawrence S. Brown, Tom Holme
Publisher:Lawrence S. Brown, Tom Holme
Chapter11: Chemical Kinetics
Section: Chapter Questions
Problem 11.30PAE: The rate of the decomposition of hydrogen peroxide, H2O2, depends on the concentration of iodide ion...
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Activity 4. Let Us Do This! Answer the following problems. Write your full solution on your
answer sheet and box the final answer.
1. The reaction of peroxydisulfate ion (S2O.") with iodide ion (1) is
S:0, (aq) + 31(aq) → 250², (aq) + l'3 (aq)
From the following data collected at a certain temperature, determine the rate law and
calculate the rate constant.
Experiment
(S:Os² ] (M)
[I-] (M)
Initial Rate (M/s)
0.080
0.034
2.2 x 104
2
0.080
0.017
1.1 x 104
3
0.16
0.017
2.2 x 104
2. Consider the reaction
A > B
The rate of the reaction is 1.6 x 102 M/s. when the concentration of A is 0.35 M.
Calculate the rate constant k if the reaction is (a) first order in A and (b) second
order in A. (Do not forget to write the correct unit for rate constant, k)
Transcribed Image Text:Activity 4. Let Us Do This! Answer the following problems. Write your full solution on your answer sheet and box the final answer. 1. The reaction of peroxydisulfate ion (S2O.") with iodide ion (1) is S:0, (aq) + 31(aq) → 250², (aq) + l'3 (aq) From the following data collected at a certain temperature, determine the rate law and calculate the rate constant. Experiment (S:Os² ] (M) [I-] (M) Initial Rate (M/s) 0.080 0.034 2.2 x 104 2 0.080 0.017 1.1 x 104 3 0.16 0.017 2.2 x 104 2. Consider the reaction A > B The rate of the reaction is 1.6 x 102 M/s. when the concentration of A is 0.35 M. Calculate the rate constant k if the reaction is (a) first order in A and (b) second order in A. (Do not forget to write the correct unit for rate constant, k)
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