1. Using a Lewis acid, BF3, (+) aureal (1) undergoes a rearrangement Org. Lett 2012, 14, 4710-4713. Using arrows propose a mechanism for this rearrangement.  2. Explain why we added BF3 as an acid to the alcohol? How does it help with reaction ( 3 --> 4)?  3. What is the process’ name for (4) --> (5)? 4. going from (5) to (6)?  5. from (6) to (2)?

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter4: Polar Bonds, Polar Reactions
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Problem 23E: Summarize the relationship between pKa and acid strength by completing the following sentences: a....
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1. Using a Lewis acid, BF3, (+) aureal (1) undergoes a rearrangement Org. Lett 2012, 14, 4710-4713. Using arrows propose a mechanism for this rearrangement. 

2. Explain why we added BF3 as an acid to the alcohol? How does it help with reaction ( 3 --> 4)? 

3. What is the process’ name for (4) --> (5)?

4. going from (5) to (6)? 

5. from (6) to (2)?

AcO
AcO
AcO
AcO
BF3
BF3
H.
H.
(1)
(3)
(4)
(5)
AcO
AcO
(2)
Base: (-)OCH3
Transcribed Image Text:AcO AcO AcO AcO BF3 BF3 H. H. (1) (3) (4) (5) AcO AcO (2) Base: (-)OCH3
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