10. Which entlalpy change is involved in the reaction? A--406K]mol" Na' (a) + ag- Nal A) Hydration B) Solution C) Dissolution D) Latice energy
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- (a) What are the units usually used to express the rates ofreactions occurring in solution? (b) As the temperatureincreases, does the reaction rate increase or decrease?(c) As a reaction proceeds, does the instantaneous reactionrate increase or decrease?Given that CuBr would precipitate later than CuI in a solution containing equimolar concentrations of Br- and I-, it can be concluded that: A. Ksp,CuI < Ksp,CuBr B. Ksp,CuI > Ksp,CuBr C. Ksp,CuI = Ksp,CuBr D. Cannot be determinedThe molarity of a solution is 0.15 M in NaI (aq) at 298.15 K. A large excess of HgI2 (s) to the solution. What is the solubility (in grams) of HgI2 (s) at saturation? HgI2 (s)<------->Hg2+ (aq) + 2I- (aq) Ksp= 2.7 × 10^-29HgI2 (s) + 2I- <------> [HgI4]2- (aq) Kf= 0.75 M
- 1.1The Ksp of Ca3 (PO4 ) 2 is 1.3 × 10−26 . Estimate the solubility of this salt in units of g. L −1 . You must show any reaction equation(s) that you may think are necessary. 1.2 If a sample of solid Ca3(PO4)2 is stirred into exactly one litre of a 0.550M solution of Na3PO4, how will the solubility of the salt compare with the answer that you have obtained in question 1.1? Explain you answer in a short sentence.The Ksp of Fe3(PO4)2 is 5.51⋅10-21 M. Calculate the solubility of Fe2+ and PO43- in a saturated solution.Potassium dichromate has several industrial applications. To determine the purity of the salt that will be used in different industrial processes, a sample mass equal to 2.660 g was dissolved and quantitatively transferred to a 500.00 mL flask. An aliquot of 25.00 mL of this solution was treated with excess KI and the released iodine was titrated with 0.1000 mol L-1 sodium thiosulfate, spending 27.00 mL. Calculate the purity of the analyzed salt. Data:K = 39.10 O = 16.00 Cr = 52.00 I = 126.9 S = 32.07
- In the synthesis of hydrocarbons, the carbon source is carbon dioxide. Although the CO2 concentra?on in the atmosphere raises at a drama?c speed, point sources are probably the easier sources for a PtX process. Iden?fy 3 possible point sources, explain why CO2 is formed and what challenges each of the three CO2 streams presentsThe student then determined ΔH neutralization for the reaction of sodium hydroxide and acetic acid, using the procedure described in this module. The student added 100.0 mL of 0.8500M NaOH to 100.0 mL of 0.8404M acetic acid. Prior to and following the mixing of the acid and base solutions, the following temperature-time data were collected. g) Identify the limiting reagent and briefly explain why it is limiting. h) Find ΔH neutralization for the reaction.One litre of a saturated aqueous solution of Ag2SO4 (MW = 311.79 g mol- 1) at 25 °C is evaporated to dryness. 4.844 g of Ag2SO4 residue was produced. What is the solubility product (Ksp)?
- TypeFormulaKsp Solubility Product Constants (Ksp at 25 oC) TypeFormulaKspBromidesPbBr26.3 × 10-6AgBr3.3 × 10-13CarbonatesBaCO38.1 × 10-9CaCO33.8 × 10-9CoCO38.0 × 10-13CuCO32.5 × 10-10FeCO33.5 × 10-11PbCO31.5 × 10-13MgCO34.0 × 10-5MnCO31.8 × 10-11NiCO36.6 × 10-9Ag2CO38.1 × 10-12ZnCO31.5 × 10-11ChloridesPbCl21.7 × 10-5AgCl1.8 × 10-10ChromatesBaCrO42.0 × 10-10CaCrO47.1 × 10-4PbCrO41.8 × 10-14Ag2CrO49.0 × 10-12CyanidesNi(CN)23.0 × 10-23AgCN1.2 × 10-16Zn(CN)28.0 × 10-12FluoridesBaF21.7 × 10-6CaF23.9 × 10-11PbF23.7 × 10-8MgF26.4 × 10-9HydroxidesAgOH2.0 × 10-8Al(OH)31.9 × 10-33Ca(OH)27.9 × 10-6Cr(OH)36.7 × 10-31Co(OH)22.5 × 10-16Cu(OH)21.6 × 10-19Fe(OH)27.9 × 10-15Fe(OH)36.3 × 10-38Pb(OH)22.8 × 10-16Mg(OH)21.5 × 10-11Mn(OH)24.6 × 10-14Ni(OH)22.8 × 10-16Zn(OH)24.5 × 10-17IodidesPbI28.7 × 10-9AgI1.5 × 10-16OxalatesBaC2O41.1 × 10-7CaC2O42.3 × 10-9MgC2O48.6 × 10-5PhosphatesAlPO41.3 × 10-20Ba3(PO4)21.3 × 10-29Ca3(PO4)21.0 × 10-25CrPO42.4 × 10-23Pb3(PO4)23.0 × 10-44Ag3PO41.3 × 10-20Zn3(PO4)29.1 ×…If all other variables were kept constant, determine theeffect that the following errors would have on the calculatedpercent yield of the product. Would the yield be expected toincrease, decrease, or would there be no effect? Explainyour reasoning.– The product was insufficiently dried before weighing.– Some of the product was lost during the transfer fromthe Buchner funnel to the evaporating dish.– 7.5 mL of FeCl3 was added instead of 3.0 mL asoutlined in the procedure.– 4.587g of K2C2O4H2O was used instead of exactly4.000g .– The recrystallization step was skipped and theexperiment went straight to vacuum filtration.A first-stage recovery of magnesium from seawater is precipitationof Mg1OH22 with CaO:Mg2+(aq) + CaO(s) + H2O(l)---->Mg(OH)2(s) + Ca2+(aq) What mass of CaO, in grams, is needed to precipitate 1000lb of Mg(OH)2?