100 mL of a benzoic acid (C5H6COOH) buffer solution is made with initial concentrations of [C5H6COOH] = 0.33M and [C5H6COONa] = 0.28M. The Ka of benzoic acid is 6.3x10-5. a) What is the pH of the buffer solution initially? b) What is the pH of the buffer after the addition of 0.5g NaOH(s). c) What minimum volume of 1M HCl should be added to exceed the buffer capacity of this solution (the buffer capacity is reached when one component of the buffer is less than 10% of the other) d) How could this initial buffer be created by combining solutions of HCl and C5H6COONa? (No calculation needed, just a detailed qualitative answer)
100 mL of a benzoic acid (C5H6COOH) buffer solution is made with initial concentrations of [C5H6COOH] = 0.33M and [C5H6COONa] = 0.28M. The Ka of benzoic acid is 6.3x10-5. a) What is the pH of the buffer solution initially? b) What is the pH of the buffer after the addition of 0.5g NaOH(s). c) What minimum volume of 1M HCl should be added to exceed the buffer capacity of this solution (the buffer capacity is reached when one component of the buffer is less than 10% of the other) d) How could this initial buffer be created by combining solutions of HCl and C5H6COONa? (No calculation needed, just a detailed qualitative answer)
Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter14: Acid- Base Equilibria
Section: Chapter Questions
Problem 4RQ: A good buffer generally contains relatively equal concentrations of weak acid and conjugate base. If...
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100 mL of a benzoic acid (C5H6COOH) buffer solution is made with initial concentrations of [C5H6COOH] = 0.33M and [C5H6COONa] = 0.28M. The Ka of benzoic acid is 6.3x10-5.
a) What is the pH of the buffer solution initially?
b) What is the pH of the buffer after the addition of 0.5g NaOH(s).
c) What minimum volume of 1M HCl should be added to exceed the buffer capacity of this solution (the buffer capacity is reached when one component of the buffer is less than 10% of the other)
d) How could this initial buffer be created by combining solutions of HCl and C5H6COONa? (No calculation needed, just a detailed qualitative answer)
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