11-C. Calculate the pH at each point listed for the titration of 100.0 mL of 0.100 M cocaine (Section 9-4, Kp = 2.6 × 10-6) with 0.200 M HNO,. The points to calculate are V, = 0.0, 10.0, 20.0, 25.0, 30.0, 40.0, 49.0, 49.9, 50.0, 50.1, 51.0, and 60.0 mL. Draw a graph of pH versus V.

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Chapter15: Additional Aqueous Equilibria
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Problem 15.BCP
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Show excel table of values for the titration curve of the given problem. An example is attached as a reference for the table of values from Excel.

11-C. Calculate the pH at each point listed for the titration of
100.0 mL of 0.100 M cocaine (Section 9-4, Kp = 2.6 × 10-6) with
0.200 M HNO,. The points to calculate are V, = 0.0, 10.0, 20.0,
25.0, 30.0, 40.0, 49.0, 49.9, 50.0, 50.1, 51.0, and 60.0 mL. Draw a
graph of pH versus V.
Transcribed Image Text:11-C. Calculate the pH at each point listed for the titration of 100.0 mL of 0.100 M cocaine (Section 9-4, Kp = 2.6 × 10-6) with 0.200 M HNO,. The points to calculate are V, = 0.0, 10.0, 20.0, 25.0, 30.0, 40.0, 49.0, 49.9, 50.0, 50.1, 51.0, and 60.0 mL. Draw a graph of pH versus V.
Titration of a strong base against a strong acid
14.00
12.00
10.00
8.00
pH of solution
6.00
4.00
2.00
0.00
10
12
14
16
mL0.1000 M HBr
Vol HBr mmol OH - mmol H+
[OH-]
[H+]
pH
1
0.0200
5.000E-13
12.30
1
0.9
0.0176
5.667E-13
12.25
0.8
0.0154
6.500E-13
12.19
5
0.5
0.0091
1.100E-12
11.96
7
0.3
0.0053
1.900E-12
11.72
9
0.1
0.0017
5.900E-12
11.23
9.5
0.05
0.0008
1.190E-11
10.92
9.9
0.01
0.0002
5.990E-11
10.22
10
0.0000
1.000E-07 1.000E-07
7
10.1
0.0100
1.664E-04
3.78
10.5
0.0500
8.264E-04
3.08
11
0.1000
1.639E-03
2.79
12
0.2000
3.226E-03
2.49
15
0.5000
7.692E-03
2.11
Transcribed Image Text:Titration of a strong base against a strong acid 14.00 12.00 10.00 8.00 pH of solution 6.00 4.00 2.00 0.00 10 12 14 16 mL0.1000 M HBr Vol HBr mmol OH - mmol H+ [OH-] [H+] pH 1 0.0200 5.000E-13 12.30 1 0.9 0.0176 5.667E-13 12.25 0.8 0.0154 6.500E-13 12.19 5 0.5 0.0091 1.100E-12 11.96 7 0.3 0.0053 1.900E-12 11.72 9 0.1 0.0017 5.900E-12 11.23 9.5 0.05 0.0008 1.190E-11 10.92 9.9 0.01 0.0002 5.990E-11 10.22 10 0.0000 1.000E-07 1.000E-07 7 10.1 0.0100 1.664E-04 3.78 10.5 0.0500 8.264E-04 3.08 11 0.1000 1.639E-03 2.79 12 0.2000 3.226E-03 2.49 15 0.5000 7.692E-03 2.11
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