Determine the rate constant for this reaction if the temperature is raised to 100.0 °C, assume that theactivation energy of this reaction equal the activation energy of step 1 in the mechanism. 1: Consider the following exothermic reaction at 25.0 °C:(CH3);CBr (aq) + H2O (1) → (CH3)3COH (aq) + Br" (aq) + H* (aq)The following mechanism was obtained for this reaction:Step 1: (CH3);CBr → (CH3)3C* (aq) + Br" (aq)Ea = 89.6 kJ/molStep 2: (CH3);C (aq) + H2O (1) → (CH3);COH,* (aq), Ea 60.3 kJ/molStep 3: (CH3);COH,* (aq) → H* (aq) + (CH3)3COH (aq)Ea = 45.0 kJ/mol

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Answered: Determine the rate constant for this…

Chemistry: Principles and Reactions

8th Edition

ISBN:9781305079373

Author:William L. Masterton, Cecile N. Hurley

Publisher:William L. Masterton, Cecile N. Hurley

Chapter12: Gaseous Chemical Equilibrium

Section: Chapter Questions

Problem 57QAP: For the following reaction C(s)+2H2(g)CH4(g) K=0.26 at 1000C (3 significant figures). What is the...

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Determine the rate constant for this reaction if the temperature is raised to 100.0 °C, assume that the activation energy of this reaction equal the activation energy of step 1 in the mechanism.

1: Consider the following exothermic reaction at 25.0 °C:
(CH3);CBr (aq) + H2O (1) → (CH3)3COH (aq) + Br" (aq) + H* (aq)
The following mechanism was obtained for this reaction:
Step 1: (CH3);CBr → (CH3)3C* (aq) + Br" (aq)
Ea = 89.6 kJ/mol
Step 2: (CH3);C (aq) + H2O (1) → (CH3);COH,* (aq)
, Ea 60.3 kJ/mol
Step 3: (CH3);COH,* (aq) → H* (aq) + (CH3)3COH (aq)
Ea = 45.0 kJ/mol

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