12. Bromination of alkanes is a much slower reaction than chlorination. Which of the following is expected to be the major organic product when 2-methylbutane is allowed to react with Br₂ in the presence of light or heat? CH3 CH3CH₂CHCH3 + Br₂ light
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- Q3. 2-Bromopentane, when treated with alcoholic KOH yields a mixture of three alkenes A, B and C. Identify A, B and C. Which is predominant? Q4 Which statement below about Sn1 reactions is incorrect? (A) SN1 reactions are stepwise and have intermediates. (B) The slow step in a SN1 reaction is formation of the carbocation intermediate. (C) SN1 reactions have first order kinetics which means only the alkyl halide is involved in the rate limiting step. (D) The products of a SN1 reaction will be a pair of enantiomers. (E) An aprotic solvent is best for Sn1 reactions as they tend to help stabilize carbocation intermediates.Are there any other possible products for the following reaction in catalytic H2SO4 and H2O?Fill in necessary products reactants or reagants of these reactions. Please note the existence of enantionmers in some cases.
- Consider the following statement in reference to SN1, SN2, E1, and E2 reactions of haloalkanes. To which mechanism(s), if any, does the statement apply? Order of reactivity of haloalkanes is methyl . 1° > 2° > 3°.Consider the following statement in reference to SN1, SN2, E1, and E2 reactions of haloalkanes. To which mechanism(s), if any, does the statement apply? Order of reactivity of haloalkanes is 3°> 2°> 1°.Dialkyl peroxides are a family of compounds which can be explosive when heated. These explosions begin with the following bond fragmentation (which is then followed by other reaction steps). Which process best describes this fragmentation? E2 Elimination Heterolytic dissociation Homolytic dissociation Racemization
- Optically pure Compound 1 undergoes a reaction at room temperature with sodium methoxide (NaOCH3) in methanol to form a single isomer of Compound 2 as shown below: 1. What are the stereochemical designations (R or S) of Compound 1 and Compound 2? 2. On the basis of the structure of Compound 2 and the information on the reaction conditions, suggest which type of mechanism Compound 1 undergoes . 3. The rate of the above reaction is determined experimentally to follow second-order kinetics. Give a fully labelled sketch of a reaction coordinate diagram for the reaction. 4. draw a mechanism on a piece of paper (using curly arrows) to show the formation of Compound 2 from Compound 1 including any activated complex. 5. If the sodium methoxide is left out of the reaction mixture, Compound 2 is formed in roughly equal amounts with another compound (Compound 3). Suggest a structure for Compound 3. With reference to the mechanism of the reaction and the structure of Compound 1, explain how these…In an attempt to prepare propylbenzene, a chemist alkylated benzene with 1-chloropropane and aluminum chloride. However, two isomeric hydrocarbons were obtained in the proportion of 2: 1. What is the main product? How did this come about? Explain showing the mechanism and nomenclature of the reaction compoundsPredict the products and mechanisms of the following reactions. When if more than one product or mechanism is possible, explain are the most probable. (d) 2-chloro-2-methylbutane by heating in ethanol (e) isobutyl iodide, KOH in ethanol / water
- What will be the major product obtained from the reaction of Br2 with 1-butene if the reaction is carriedout ina. dichloromethane? b. water? c. ethyl alcohol? d. methyl alcohol?Bromine reacts with alkenes in methanol according to the equation (see image 1). When this reaction was carried out with 4-tert-butylcyclohexene, only one isomer was formed with the molecular formula C12H23BrO (80% yield) a) Which of the following is the structure more reasonable for this compound? (see image 2) b) Explain your reasoning through a corresponding mechanismIn the reaction of NaBH4 with formaldehyde in methanol sovlent, the products are BH3, CH3OH and sodium methoxide. what is the transition state for the slow step of this reaction? please give structure.