1,3,5-heptatrienyl radical (an open chain of seven carbon atoms) has the following roots for the Huckel polynomial: x--1.85, -v2, -0.77, 0, +0.77, +v2, +1.85 a) Derive the resonance energy of the 1,3,5-heptatrienyl radical. Ieido l oot ors avmd (unioy 0g enos Y b) Derive the structure for the p-orbital corresponding to the root x +v2.

Organic Chemistry
8th Edition
ISBN:9781305580350
Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Publisher:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
Chapter20: Dienes, Conjugated Systems, And Pericyclic Reactions
Section20.3: Uv-visible Spectroscopy
Problem 20.5P
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1,3,5-heptatrienyl radical (an open chain of seven carbon atoms) has the following
roots for the Huckel polynomial:
x=-1.85, -V2, -0.77, 0, +0.77, +V2, +1.85
comb
a) Derive the resonance energy of the 1,3,5-heptatrienyl radical.
io la n
taido ni nostls lon soft sond
arl avimd (anio 0
b) Derive the structure for the p-orbital corresponding to the root x +v2.
Transcribed Image Text:1,3,5-heptatrienyl radical (an open chain of seven carbon atoms) has the following roots for the Huckel polynomial: x=-1.85, -V2, -0.77, 0, +0.77, +V2, +1.85 comb a) Derive the resonance energy of the 1,3,5-heptatrienyl radical. io la n taido ni nostls lon soft sond arl avimd (anio 0 b) Derive the structure for the p-orbital corresponding to the root x +v2.
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