16, cont'd) (b) of the cis- and trans- alkene products, predict the major product of the reaction. Indicate whether your predicted major product is the Zaitsev product or non-Zaitsev/Hofmann product. Justify your response for your choice of major product using Newman projections and drawing(s) of the relevant transition state(s). Your justification should include rationales for how BOTH products could arise (not just one), and why one is favored. To facilitate your answer to the part (c), you may label your transition states and products with letter abbreviations here (e.g. A, B, C, etc.).

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter15: Radical Reactions
Section: Chapter Questions
Problem 11E
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please answer question b and c

NaOCH3
(S)-1-chloro-1,2-diphenylethane
do ano
cis-1,2-diphenylethene trans-1,2-diphenylethene
+ NaCl
+
- HOCH3
Transcribed Image Text:NaOCH3 (S)-1-chloro-1,2-diphenylethane do ano cis-1,2-diphenylethene trans-1,2-diphenylethene + NaCl + - HOCH3
16, cont'd) (b) of the cis- and trans- alkene products, predict the major product of the reaction.
Indicate whether your predicted major product is the Zaitsev product or non-Zaitsev/Hofmann
product. Justify your response for your choice of major product using Newman projections and
drawing(s) of the relevant transition state(s). Your justification should include rationales for how
BOTH products could arise (not just one), and why one is favored. To facilitate your answer to
the part (c), you may label your transition states and products with letter abbreviations here (e.g.
A, B, C, etc.).
(c) Draw a reaction coordinate diagram of the reaction that depicts the starting materials,
products, and transition states. Which energy difference in your diagram is reflected in the
reaction outcome (e.g. difference in energy between products vs. transition states)? If you labeled
the relevant species in part (b) with abbreviations, you may use the abbreviations in your reaction
coordinate diagram.
Energy
O
JA) (300)) Lobosea sednice of emotions to questo posto gde geborg dejta
Transcribed Image Text:16, cont'd) (b) of the cis- and trans- alkene products, predict the major product of the reaction. Indicate whether your predicted major product is the Zaitsev product or non-Zaitsev/Hofmann product. Justify your response for your choice of major product using Newman projections and drawing(s) of the relevant transition state(s). Your justification should include rationales for how BOTH products could arise (not just one), and why one is favored. To facilitate your answer to the part (c), you may label your transition states and products with letter abbreviations here (e.g. A, B, C, etc.). (c) Draw a reaction coordinate diagram of the reaction that depicts the starting materials, products, and transition states. Which energy difference in your diagram is reflected in the reaction outcome (e.g. difference in energy between products vs. transition states)? If you labeled the relevant species in part (b) with abbreviations, you may use the abbreviations in your reaction coordinate diagram. Energy O JA) (300)) Lobosea sednice of emotions to questo posto gde geborg dejta
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