16) What products are formed from reaction of one mole HCL with this ether? (Hint: Cl- is a weak nucleophile) CH3 H3C-CH₂-O-C-CH3 CH3 O a. tert-butyl chloride + chloroethane O b. tert-butyl chloride + ethanol c. tert-butyl alcohol + chloroethane Od. tert-butyl alcohol + ethanol e. tert-butyl alcohol + tert-butyl chloride

16) What products are formed from reaction of one mole HCL with this ether? (Hint: Cl- is a weak nucleophile) CH3 H3C-CH₂-O-C-CH3 CH3 O a. tert-butyl chloride + chloroethane O b. tert-butyl chloride + ethanol c. tert-butyl alcohol + chloroethane Od. tert-butyl alcohol + ethanol e. tert-butyl alcohol + tert-butyl chloride

Organic Chemistry: A Guided Inquiry

2nd Edition

ISBN:9780618974122

Author:Andrei Straumanis

Publisher:Andrei Straumanis

Chapter14: Elimination

Section: Chapter Questions

Problem 18E

See similar textbooks

Similar questions

II. Alcohols in Synthesis B.) How are alcohols used to make ethers in the Williamson ether synthesis? How do you design the synthesis of ethers using both acidic and basic Williamson ether synthesis strategies?
K for enolization of 2,4-cyclohexadienone is about 1013. Explain why the enol is so much more stable than the keto tautomer.
2-Methylpropane have more than one kind of hydrogen and will generate 2 different products with bromination in the presence of uv light. t or f
What is reaction 1 and 2 called? Choices: A. Williamson ether synthesis, B. Reduction with Grignard reagent, C. Acidic ether cleavage, D. FC Alkylation What are the reagents for reaction 1 and 2? Choices: A. methanol in acidic medium, B. sodium hydride and bromomethane, C. methyl bromide and aluminum bromide, D. methanoyl bromide
Which of the following scientific statements are true and which are false? 1- [ ] Symmetric ethers are generally synthesized by dehydration of alkyne. 2- [ ] 2 molecules of Formaldehyde react together to form Aldol product. 3- [ ] Electrophilic aromatic substitution is the characteristic reactions for alcohols. 4- [ ] The SN1 reaction occurs with inversion of configuration. 5- [ ] In acid dehydration of 2-methyl butanol the major product is 2- methyl-2-butene. 6- [ ] Rate of formation of carbocations follow the order 3˚ > 2˚> 1˚> CH3+ 7- [ ] Hemiacetal produces when one mole of alcohol added to aldehyde. 8- [ ]Cyclohexanol is oxidized to a ketone using Jone's reagent. 9- [ ] Mixture of equal parts of enantiomers is called racemic compound. 10- [ ] E1 describes an elimination reaction in which the rate-…
1. Explain the solubility behavior of the alcohols and phenols in water as a function of: a. Branching in the structure b. Relative proportion of hydrophilic to hydrophobic bonds 2. Based on oxidation test, classify the alcohols and phenols according to the following categories: easily oxidizable, oxidizable, and resistant to oxidation. 3. Explain in 2 – 3 sentences the reactivity differences of the alcohols towards the Lucas reagent. 4. Explain in 2 – 3 sentences the solubility of alcohols and phenols in water.
What product(s) would you expect to obtain from reaction of 1, 3-cyclohexadiene witheach of the following?(a) 1 mol Br2in CH2Cl2(b) O3followed by Zn(c) 1 mol HCl in ether(d) 1 mol DCl in ether(e) 3-Buten-2-one (H2C = CHCOCH3)(f) Excess OsO4, followed by NaHSO3
Explain why the reaction of 2-bromopropane with NaOCOCH3 gives (CH3)2CHOCOCH3 exclusively as product, but the reaction of 2-bromopropane with NaOCH2CH3 gives a mixture of (CH3)2CH3 (20%) and CH3CH = CH2 (80%).
Explain how the reaction of (CH3)2CHCH(Cl)CH3 with H2O yields two substitutionproducts, (CH3)2CHCH(OH)CH3 and (CH3)2C(OH)CH2CH3
Draw a stepwise mechanism for the following reaction that illustrates how two substitution products are formed. Explain why 1-bromohex-2ene reacts rapidly with a weak nucleophile (CH3OH) under SN1 reaction conditions, even though it is a 1 ° alkyl halide.
Kinetic and thermodynamic enol products Of 2-butanone conditions? Factors that affect Rate of reaction?...
Would you expect the reactivity of a five-membered ring ether such as tetrahydrofuran (Table 10.2) to be more similar to the reactivity of an epoxide or to the reactivity of a noncyclic ether? Why?