16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. N(CH3)3 deact CH,N(CH3)3 A meta N(CH,)2 -CH3 act act
16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. N(CH3)3 deact CH,N(CH3)3 A meta N(CH,)2 -CH3 act act
Chapter16: Chemistry Of Benzene: Electrophilic Aromatic Substitution
Section16.SE: Something Extra
Problem 25VC: The following molecular model of a dimethyl-substituted biphenyl represents the lowest-energy...
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Question 16.46
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The availability of lone pairs on N-atom makes it more reactive while the presence of positive charge on N-atom will inactivates the ring for electrophilic type of substitution.
The activated groups will generally direct the electrophile to para and ortho positions.
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