17-28. At 400 K oxalic acid decomposes according to H,C,O,(g) → CO,(g) + HCHO,(g) The rate of this reaction can be studied by measure- ment of the total pressure. Determine the rate law and the value of the rate constant of this reaction from the following measurements that give the total pressure reached after 2.00 × 10ª seconds from the given starting pressure of oxalic acid: PH,C,0,/Torr (at t = 0) Protal/Torr (at t = 2.00 × 104 s) 5.0 7.2 7.0 10 8.4 12

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter14: Chemical Kinetics: The Rates Of Chemical Reactions
Section: Chapter Questions
Problem 86IL: The acid-catalyzed iodination of acetone CH3COCH3(aq) + I2(aq) CH3COCH2I(aq) + HI(aq) is a common...
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17-28. At 400 K oxalic acid decomposes according to
H,C,O,(g) → CO,(g) + HCHO,(g)
The rate of this reaction can be studied by measure-
ment of the total pressure. Determine the rate law
and the value of the rate constant of this reaction
from the following measurements that give the total
pressure reached after 2.00 × 10ª seconds from the
given starting pressure of oxalic acid:
Piyc40,/Torr
(at t= 0)
Potal/Torr
(at t= 2.00 × 104 s)
5.0
7.2
7.0
10
8.4
12
Transcribed Image Text:17-28. At 400 K oxalic acid decomposes according to H,C,O,(g) → CO,(g) + HCHO,(g) The rate of this reaction can be studied by measure- ment of the total pressure. Determine the rate law and the value of the rate constant of this reaction from the following measurements that give the total pressure reached after 2.00 × 10ª seconds from the given starting pressure of oxalic acid: Piyc40,/Torr (at t= 0) Potal/Torr (at t= 2.00 × 104 s) 5.0 7.2 7.0 10 8.4 12
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