By applying the steady-state hypothesis to the species CH3' and C2H5* show that the mechanism: C2H6 > 2 CH3' CH3 + C2H6 > CH4+ C2H5' C2H5' → C2H4+ H• C2H6 + H. → H2 + C2H5* 2 C2H5' → C4H10 would lead to an overall rate law of one-half order

Chemistry: The Molecular Science
5th Edition
ISBN:9781285199047
Author:John W. Moore, Conrad L. Stanitski
Publisher:John W. Moore, Conrad L. Stanitski
Chapter11: Chemical Kinetics: Rates Of Reactions
Section: Chapter Questions
Problem 97QRT
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By applying the steady-state hypothesis to the species CH3' and C2H5' show that the mechanism:
C2H6 > 2 CH3
CH3* + C2H6 → CH4+ C2H5'
C2H5: → C2H4+ H•
C2H6 + H. → H2 + C2H5'
2 C2H5' → C4H10
would lead to an overall rate law of one-half order
Transcribed Image Text:By applying the steady-state hypothesis to the species CH3' and C2H5' show that the mechanism: C2H6 > 2 CH3 CH3* + C2H6 → CH4+ C2H5' C2H5: → C2H4+ H• C2H6 + H. → H2 + C2H5' 2 C2H5' → C4H10 would lead to an overall rate law of one-half order
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