19.27a) What sign for AS do you expect when the volume of 0.200 mol of an ideal gas at 27 °C is increased isothermally from an initial volume of 10.0 L? (b) If the final volume is 18.5 L, calculate the entropy change for the process. (c) Do you need to specify the temperature to calculate the entropy change?

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter13: Spontaneous Processes And Thermodynamic Equilibrium
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Please help me answer question 19.27 thank you very much
of the system decreases. What can you con-
process
clude ab the sign and magnitude of ASu? (c) During
a certainversible process, the surroundings undergo an
entropy ange, ASurr-781/K. What is the entropy
change of the system for this process?
19.38
19.27 a) What sign for AS do you expect when the volume of
0.200 mol of an ideal gas at 27 °C is increased isothermally
from an initial volume of 10.0 L? (b) If the final volume
is 18.5 L, calculate the entropy change for the process.
(c) Do you need to specify the temperature to calculate the
entropy change?
19.39
19.28 (a) What sign for AS do you expect when the pressure on
0.600 mol of an ideal gas at 350 K is increased isothermally
from an initial pressure of 76.0 kPa? (b) If the final pres-
sure on the gas is 121.6 kPa, calculate the entropy change
for the process. (c) Do you need to specify the temperature
to calculate the entropy change?
19.46
The Molecular Interpretation of Entropy and the
Third Law of Thermodynamics (Section 19.3)
19.29 For the isothermal expansion of a gas into a vacuum,
AE 0,q 0, and w 0. (a) Is this a spontaneous pro-
"driving force" for the expan-
SESS? (b) Explain why no work is done by the system during
Transcribed Image Text:of the system decreases. What can you con- process clude ab the sign and magnitude of ASu? (c) During a certainversible process, the surroundings undergo an entropy ange, ASurr-781/K. What is the entropy change of the system for this process? 19.38 19.27 a) What sign for AS do you expect when the volume of 0.200 mol of an ideal gas at 27 °C is increased isothermally from an initial volume of 10.0 L? (b) If the final volume is 18.5 L, calculate the entropy change for the process. (c) Do you need to specify the temperature to calculate the entropy change? 19.39 19.28 (a) What sign for AS do you expect when the pressure on 0.600 mol of an ideal gas at 350 K is increased isothermally from an initial pressure of 76.0 kPa? (b) If the final pres- sure on the gas is 121.6 kPa, calculate the entropy change for the process. (c) Do you need to specify the temperature to calculate the entropy change? 19.46 The Molecular Interpretation of Entropy and the Third Law of Thermodynamics (Section 19.3) 19.29 For the isothermal expansion of a gas into a vacuum, AE 0,q 0, and w 0. (a) Is this a spontaneous pro- "driving force" for the expan- SESS? (b) Explain why no work is done by the system during
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