(2) Consider a fictitious system, whose Helmholtz free energy is expressed asF(T,V,N) NRT 1 - α--(1-ax).where T,V,N are temperature, volume, number of particles, respectively. R, a are positiveconstants. Note that the equation of state for ideal gas does not apply to this system.(a) Calculate the pressure.(b) Obtain Gibbs free energy as a function of (T,p,N) by using pressure p and Legendretransform: F(T,V,N) → G(T,p,N).OGдр(c) From the definition of Gibbs free energy, what thermodynamic quantity should give?Does G(T,p,N) above give this quantity?(d) The fictitious Helmholtz free energy in this problem has an undesirable property. Explainwhy this F is not expected to exist in reality.

Answered: Image /qna-images/answer/8aad6472-82ee-4e19-8208-9482c736adeb.jpg

Answered: (2) Consider a fictitious system, whose…

University Physics Volume 2

18th Edition

ISBN:9781938168161

Author:OpenStax

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Chapter2: The Kinetic Theory Of Gases

Section: Chapter Questions

Problem 2.4CYU: Check Your Understanding If you consider a very small object, such as a grain of pollen, in a gas,...

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