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- Show how to prepare each Gilman reagent in Example 15.4 from an appropriate alkyl halide and each epoxide from an appropriate alkene.What is the best choice of reagents to achieve the following reaction? A. SOCl2 (1/2 equivalent) B. KOH (pellets) C. K2SO4 D. PhCO2NaFor problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent. (g) Sodium methanethiolate (NaSCH3) in ethanol
- For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent. (d) Sodium cyanide in dimethyl sulfoxide (e) Sodium azide in aqueous ethanol (f) Sodium hydrogen sulfide in ethanolA. OsO4 and NMO B. Br2 and H20 C. Hg(OAc)2, H2O and NaBH4, NaOH D. RCO3H E. BH3-THF and H2O2, NaOH Which reagent will complete this reaction?Can you match best nucleophile / conditions from the list that will give a successful hydrolysis reaction for each electrophile? (there's one best nucleophile / conditions for each electrophile) <List for Nucleophile / condition> a. LiAlH4; hydronium work-up b. PCC c. NaH d. CrO3 e. HOEt f. H3O+ or OH- g. H2O h. NaBH4;hydronium work-up Electrophile 1. Acid chloride 2. Acetic anhydride 3. Ester 4. Amide I'm asking again on bartleby because pther tutor gave me the right answer because I think I didn't make my question clear enough.
- Which compound will undergo solvolysis most rapidly? A. t-hexyl-I B. t-hexyl-OSO2CH3 C. t-hexyl-F D. t-hexyl-OSO2CF3The following reaction has a ΔSsystem < 0 O2(g) → 2O(g) T or F can you explain why this is false?Draw the products formed when benzoyl chloride (C6H5COCl) is treated with each nucleophile: (a) H2O, pyridine; (b) CH3COO-; (c) NH3 (excess); (d) (CH3)2NH (excess).
- Draw the substitution product formed (including stereochemistry) when (R)-hexan-2-ol is treated with each series of reagents: (a) NaH, followed by CH3I; (b) TsCl and pyridine, followed by NaOCH3; (c) PBr3, followed by NaOCH3. Which two routes produce identical products?For problem 8.17, all of the reactions will be SN2. For each reaction, identify and evaluate each nucleophile (strong? weak? Strong or weak as a base?) Also, evaluate each solvent as polar protic or polar aprotic. I recommend drawing the structure of each solvent.What is the name of reaction 2? a Grignard reaction b Reduction c Acetal formation d Williamson ether synthesis Which of the following is product B? a Methoxycyclopentane b 1-methylcyclopentan-1-ol c 1,2-methoxycyclopentane d Cyclopentanone