2. (20%). (a) Write all reactions and equations for a closed carbonate system except for the charge balance equation.(b) Derive the equations for [H:CO,"), [HCO: ], and [CO] written as a function of [H], Cr. K.i, and K.2.(c) Derive the equations for log[H:CO, ] as a function of pH and logCr if pH is lower than pK,t.(d) Repeat Part (c) if pH is between pKai and pK.2.(c) Repeat Part (c) if pH is above pK.

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2. (20%). (a) Write all reactions and equations for a closed carbonate system except for the charge balance equation. (b) Derive the equations for [H:CO"J, [HCO; ], and (CO; ] written as a function of (H'], Cr. Kai, and K.2. (c) Derive the equations for log[H;CO,"] as a function of pH and logCy if pH is lower than pK. (d) Repeat Part (c) if pH is between pK. and pK.2. (e) Repeat Part (c) if pH is above pK..

2. (20%). (a) Write all reactions and equations for a closed carbonate system except for the charge balance equation. (b) Derive the equations for [H:CO"J, [HCO; ], and (CO; ] written as a function of (H'], Cr. Kai, and K.2. (c) Derive the equations for log[H;CO,"] as a function of pH and logCy if pH is lower than pK. (d) Repeat Part (c) if pH is between pK. and pK.2. (e) Repeat Part (c) if pH is above pK..

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter7: Statistical Data Treatment And Evaluation

Section: Chapter Questions

Problem 7.26QAP

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