2. a. Copper(II) acetate is a dimer, and the two copper atoms are strongly interacting. The epr spectrum consists of seven lines with intensity ratios 1:2:3:4:3:2:1. Copper nuclei have an / value of ½, and copper acetate consists of a ground state that is a singlet and an excited state that is a triplet. Explain the number and relative intensity of the lines in the spectrum. [For answer, see B. Bleaney and K. D. Bowers, Proc. Roy. Soc. (London), A214, 451 (1952).] b. What would you expect to happen to the signal intensity as a sample of copper acetate is cooled? Why?
2. a. Copper(II) acetate is a dimer, and the two copper atoms are strongly interacting. The epr spectrum consists of seven lines with intensity ratios 1:2:3:4:3:2:1. Copper nuclei have an / value of ½, and copper acetate consists of a ground state that is a singlet and an excited state that is a triplet. Explain the number and relative intensity of the lines in the spectrum. [For answer, see B. Bleaney and K. D. Bowers, Proc. Roy. Soc. (London), A214, 451 (1952).] b. What would you expect to happen to the signal intensity as a sample of copper acetate is cooled? Why?
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter6: Electronic Structure And The Periodic Table
Section: Chapter Questions
Problem 66QAP: Consider the following transitions 1. n=3 to n=1 2. n=2 to n=33. n=4 to n=34. n=3 to n=5(a) For...
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![2.
a. Copper(II) acetate is a dimer, and the two copper atoms are strongly interacting.
The epr spectrum consists of seven lines with intensity ratios 1:2:3:4:3:2:1.
Copper nuclei have an I value of 2, and copper acetate consists of a ground state
that is a singlet and an excited state that is a triplet. Explain the number and relative
intensity of the lines in the spectrum. [For answer, see B. Bleaney and K. D. Bowers,
Proc. Roy. Soc. (London), A214, 451 (1952).]
b. What would you expect to happen to the signal intensity as a sample of copper
acetate is cooled? Why?](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fb394a4da-0854-48f5-8f42-bbfa6d7bcc65%2F790bb402-ca01-4f63-bef7-c9ff32ce70f8%2Fjwa85pg_processed.jpeg&w=3840&q=75)
Transcribed Image Text:2.
a. Copper(II) acetate is a dimer, and the two copper atoms are strongly interacting.
The epr spectrum consists of seven lines with intensity ratios 1:2:3:4:3:2:1.
Copper nuclei have an I value of 2, and copper acetate consists of a ground state
that is a singlet and an excited state that is a triplet. Explain the number and relative
intensity of the lines in the spectrum. [For answer, see B. Bleaney and K. D. Bowers,
Proc. Roy. Soc. (London), A214, 451 (1952).]
b. What would you expect to happen to the signal intensity as a sample of copper
acetate is cooled? Why?
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