The spectra that you observe are for approximately 1 x 1012 atoms. So it is likely, that with electronic excitation, many of the electronic energy levels will be readily populated. However, the higher energy levels will be less populated, so what does say about the intensity of the higher energy peaks? Is that observation consistent with the spectrum we measured with the spectrometer?

Physical Chemistry
2nd Edition
ISBN:9781133958437
Author:Ball, David W. (david Warren), BAER, Tomas
Publisher:Ball, David W. (david Warren), BAER, Tomas
Chapter15: Introduction To Electronic Spectroscopy And Structure
Section: Chapter Questions
Problem 15.5E
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The spectra that you observe are for approximately 1 x 1012 atoms. So it is likely, that with electronic excitation, many of the electronic energy levels will be readily populated. However, the higher energy levels will be less populated, so what does say about the intensity of the higher energy peaks? Is that observation consistent with the spectrum we measured with the spectrometer?

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