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- Drawing on what you know about the stereochemistry of alkene addition reactions, a. write the mechanism for the reaction of 2-butyne with one equivalent of Br2. b. predict the configuration of the product of the reaction.You are required to synthesize 2-bromopentane from the reaction between an alkene with HBr. Which alkene, 1-pentene or 2-pentene, should you react with HBr in order to get 2-bromopentane? Give an explanation.Given the solution to Example 8.5, predict the structure of the product(s) formed when 3-hexene is treated with NBS.
- Drawing on what you know about the stereochemistry of alkene addition reactions, a. write the mechanism for the reaction of 2-butyne with one equivalent of Br2. A. predict the configuration of the product of the reaction.What’s the role of NaBH4 in Oxymercuration-Demercuration of cyclohexene?An unknown hydrocarbon G, whose formula is C16H26 contains two triple bonds. Ozonolysis followed by reduction with (CH3)2S gave CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. Suggest a reasonable structure for compound G.
- A chemist allows some pure (2S,3R)-3-bromo-2,3-diphenylpentane to react with a solution of sodium ethoxide(NaOCH2CH3) in ethanol. The products are two alkenes: A (cis-trans mixture) and B, a single pure isomer. Under thesame conditions, the reaction of (2S,3S)-3-bromo-2,3-diphenylpentane gives two alkenes, A (cis-trans mixture) and C.Upon catalytic hydrogenation, all three of these alkenes (A, B, and C) give 2,3-diphenylpentane. Determine the structuresof A, B, and C; give equations for their formation; and explain the stereospecificity of these reactionsPlease tell the outcome of the addition of HBr to (a) trans-2-pentene, (b) 2-methyl-2-butene, and (c) 4-methylcyclohexene. Also please list how many isomers can be formed in each case.Treatment of propylbenzene with NBS + hv affords a single constitutional isomer. Suggest a structure for the product and a reason for its formation.
- is steric hinderance not an issue here? why when reacting with KOC(CH3)3 does it yield 2-isopropyl-1-pentene and it yields 2,3-dimethyl-2hexene here?2-bromopentane, when treated with alcoholic KOH yields a mixture of three alkenes A, B and C. Identify A, B and C. Which is predominant?Predict the organic product(s) of the reaction of 2-butene with each reagent. Q.) Cl2 in H2O