An alkane with the molecular formula C3H18 forms only one monochlorinated product when heated with Cl2 . Propose a structure for the alkane. 1.

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An alkane with the molecular formula C3H18 forms only one monochlorinated product when
heated with Cl, . Propose a structure for the alkane.
1.
2.
Arrange the following in order of increasing rate of reaction with Br, and UV light
CH;CH=CHCH3
(a)
(CH3);CC(CH3)3
(b)
(C,H5);CH
(c)
(CH3);CH
(d)
least reactive
most reactive
How many distinct monochlorinated products, including stereoisomers, can result when the
alkane below is heated in the presence of Cl2?
3.
A) 2
В) 4
С) 5
D) 6
E) 8
4.
The reaction Br2 + CH3B1 → CH2B12 + HBr was carried out. Which of the following
mechanism steps is both productive and relatively likely to occur?
A) Br · +· CH2B1 → CH2B12
В) Br : + CH3 — СНҙBr
C) Br · + Br2 –→ Br2 + Br ·
D) Br · + CH3Br → HBr + · CH2B1
5.
Which of the following is true about the halogenation of methane, CH4?
A) The activation energy for F · + CH4 →· CH3 + HF is larger than any other halogen.
B) 02 slows these reactions by inhibiting the termination step.
C) The activation energy for I· + CH4 →· CH3 + HI is relatively small.
D) The reaction must take place in the liquid state.
E) I2 is unreactive because the activation energy for I · + CH4 → · CH3 + HI is relatively large.
Transcribed Image Text:An alkane with the molecular formula C3H18 forms only one monochlorinated product when heated with Cl, . Propose a structure for the alkane. 1. 2. Arrange the following in order of increasing rate of reaction with Br, and UV light CH;CH=CHCH3 (a) (CH3);CC(CH3)3 (b) (C,H5);CH (c) (CH3);CH (d) least reactive most reactive How many distinct monochlorinated products, including stereoisomers, can result when the alkane below is heated in the presence of Cl2? 3. A) 2 В) 4 С) 5 D) 6 E) 8 4. The reaction Br2 + CH3B1 → CH2B12 + HBr was carried out. Which of the following mechanism steps is both productive and relatively likely to occur? A) Br · +· CH2B1 → CH2B12 В) Br : + CH3 — СНҙBr C) Br · + Br2 –→ Br2 + Br · D) Br · + CH3Br → HBr + · CH2B1 5. Which of the following is true about the halogenation of methane, CH4? A) The activation energy for F · + CH4 →· CH3 + HF is larger than any other halogen. B) 02 slows these reactions by inhibiting the termination step. C) The activation energy for I· + CH4 →· CH3 + HI is relatively small. D) The reaction must take place in the liquid state. E) I2 is unreactive because the activation energy for I · + CH4 → · CH3 + HI is relatively large.
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