2. Provide reagents/conditions to accomplish the following syntheses. Several steps are required in some cases. (a) EIO (b) hint: direct alkylation by BuX is not favoured
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- An unknown hydrocarbon G, whose formula is C16H26 contains two triple bonds. Ozonolysis followed by reduction with (CH3)2S gave CH3(CH2)4CO2H and HO2CCH2CH2CO2H as the only products. Suggest a reasonable structure for compound G.Suggest ways of synthesizing the compound, how would youmake the disconnections and what are the synthons?write the mechanism and predict the product, and includ the stereochemistry
- Provide Examples of dehydrohalogenation of dihalides to afford alkynes ?Provide the E2 mechanism for β-elimination reactionemploying 2-chloro-2-methylbutane to prepare 2-methyl-2-butene and 2-methyl-1-butene reaction. Use the actual structures of thereactants and products. Explain which of the alkenes is the major product ofthis reaction ?2 Provide the structure(s) of the expected major organic product(s) (where appropriate) and provide a detailed, reasonable, arrow-pushing mechanism. Hint: In the presence of a-keto acids, NR3 selectively reacts with the keto motif - not the carboxylic acid end.
- Provide one alkyl halide of your choice and discuss its structure, nomenclature (systematic and common), physical properties, method/s of preparation, and applications.Predict the products of the following reduction reactions, including stereochemistry where needed. If the reaction product is racemic, indicate that by writing “racemic”. please explain stepsGive the structures of two different alkyl bromides both of which yield the indicated alkene as the exclusive product of E2 elimination.
- Give the structure of the product and/or intermediates of the following reactions. Indicate, where appropriate, both regiochemistry and stereochemistry.The hydroboration–oxidation of internal alkynes produces ketones.(a) When hydroboration–oxidation is applied to but-2-yne, a single pure product isobtained. Determine the structure of this product, and show the intermediates in itsformation.I'm curious, can a decyclization or some chemical reaction to eliminate sulfur take place here, possibly forming SO2? and besides that, I would like you to give me examples of deciclizations of heterocycles, if they are possible, I honestly don't know