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- Illustrated below is the hydrolysis of a C-C bond (in the first molecule) hydrolyzed by water (2nd molecule). Which pair of open boxes best identifies the location of the (-H) and (-OH) components of water on the products. Choose one from the following: (a) A (b) B (c) C (d) DLooking for compound B and E . Thank YouCompound X is insoluble in cold KMnO4, Br2 in CCl4, and conc. H2SO4. Compound X is most likely: a. an alkane b. none of these c. an alkene d. an alcohol e. an alkyl halide Indicate which of the ff. statements regarding nucleophilicity is incorrect. F- is more nucleophilic, hence, more reactive towards methyl iodide than Cl-. Second row elements are more nucleophilic than first row elements of comparable basicity. The rate of SN2 reaction may be markedly affected by the nucleophilicity of the attacking atom. Nucleophilicity is the affinity of a nucleophile to an electrophilic carbon Which of the following alkynes can be deprotonated by NaNH2 in liquid NH3? 3-Methylhex-2-yne Pent-2-yne 3-Methylbutyne none of these Hex-3-yne
- Compound A is first reacted with methylamine in the presence of acid and then treated with NaBH3CN. Using the spectroscopic data given, what is the structure of the product after step 1?Show how HC≡CH, CH3CH2Br, and (CH3)2CHCH2CH2Br can be used to prepare CH3CH2C≡CCH2CH2CH(CH3)2. Show all reagents, and use curved arrows to show movement of electron pairs.Rank A, B, and C in order of increasing SN1 reactivity.
- Will the bonding of the Zn2+ ion to the ketone oxygen lone pair make theketone C=O easier or more difficult to reduce? Why?The compound whose structure is shown here is acetyl acetone. It exists in two forms:the enol form and the keto form The molecule reacts with OH–to form an anion, [CH3COCHCOCH3] (often abbreviatedacac–for acetylacetonate ion). One or the most interesting aspects of this anion is thatone or more of them can react with transition metal cations to give stable, highlycolored compounds (a) Are the keto and enol forms of acetylacetone resonance forms? Explain youranswer.(b) What is the hybridization or each atom (except H) in the enol form? What changesin hybridization occur when it is transformed into the keto form?(c) What are the electron-pair geometry and molecular geometry around each C atomin the keto and enol forms? What changes in geometry occur when the keto formchanges to the enol form?(d) Draw three possible resonance structures for the acac–ion.(e) Is cis-trans isomerism possible in either the enol or the keto form of acetylacetone?(f) Is the enol form of acetylacetone polar?…If a small amount of aqueous Br2 is added to A, the reddish color of Br2 persists, but the color disappears when Br2 is added to B. When the aziridiniumion reacts with methanol, only A is formed. Identify A and B.