2. State CLEARLY how you would differentiate between primary, secondary, and tertiary alcohols shown below using chemical reactions and state the observation that would be seen for type of alcohols OH A CH3 CH3 HO & S LOH B C
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- Reaction of -pinene with borane followed by treatment of the resulting trialkylborane with alkaline hydrogen peroxide gives the following alcohol. Of the four possible cis,trans isomers, one is formed in over 85% yield. (a) Draw structural formulas for the four possible cis,trans isomers of the bicyclic alcohol. (b) Which is the structure of the isomer formed in 85% yield? How do you account for its formation? Create a model to help you make this prediction.COMPLETE THE TWO REACTIONS BELOWIn the box provided beneath each structure below, write in the oxidation state for the starred carbon within that compound.
- Reduction of 4-tert-butylcyclohexanoneIntroductionOne of the last topics covered in Organic I was the reduction of carbonyl containing compounds such asaldehydes, ketones, esters, and carboxylic acids. Reduction can be defined in many different ways: oneof which is the increase in hydrogen atoms in the compound. One of the most important reactions forsynthesizing primary and secondary alcohols is through the reduction of aldehydes and ketones byadding H2 across carbonyl double bond. One of the most common methods to achieve thistransformation is through a metal hydride delivery agent such as lithium aluminum hydride (LAH) orsodium borohydride (NaBH4).The first step in this reaction is the transfer of a hydride ion to the carbon of the carbonyl. The hydrideacts as a nucleophile and attacks the carbon of the carbonyl. The hydride can either come in via anaxial attack or an equatorial attack depending on steric factors and the placement of other substituentson the ring. Below is the…i. Define Hemiacetal, Acetal and Ketal. ii. Give the structure of the product formed from the reaction of propanal with 1M ethanol in dry acid. iii. What happens when Further 1M of ethanol is added to above?you wish to produce n-butyl methyl ether from n-butyl bromide and sodium methoxide. Write a breif but complete description of how you would carry out this reaction. Break the procedure into the unit operations involved e.g. reaction, filtration, drying , distillation.
- How is the mechanism for oxymercuration/demercuration reactions of alkenes understood? How are the (Markovnikov) products predicted and what reagents would you need to use to incorporate this reaction into a multistep synthesis strategy. Finally, what makes this a potentially more useful way to synthesize alcohols from alkenes than simple acid hydration?(i) Name, draw and describe the organic product of the reaction between 2-methylbut-1-ene and H2O in the presence of H2SO4 and provide a clear rationale as to why this is the major product of the reaction. (ii) The elimination reaction between 2-bromobutane and NaOCH2CH3 gives two organic products. Draw a mechanism for the reaction which produces the major organic elimination product and provide a rationale as to why that is the major product.When the hypochlorite oxidation is performed on secondary alcohols such as 1-phenolethanol, the product of the reaction is benzoate ion and trichloromethane if an excess of hypochlorite is used in the absence of a buffer to keep the pH below 10. Explain the formation of these products (Hint: what reaction do the products remind you of?) Provide a complete mechanism?
- Can someone go through the logistics behind this question? For Compound X, all I know is that because it reacts with chromic acid, it would probably be a primary or secondary alcohol. However, I don't know what the Na+ is supposed to do or how the bromine and lucas reagents work. For Compound Y, I was under the impression that it would be a tertiary alcohol because it does not react/oxidize, but the answer key says it is actually a cyclic compound.1. In the reactions involving the three isomeric alcohols with the formula C4H9OH, describewhat each of the following tests showed about reactivity of the -OH group and reactions of 1°,2°, and 3° alcohols.• the test with neutral KMnO4• the test with concentrated HCl2. Predict how the fourth alcohol with the formula C4H10O would react if tested with:• 0.01 M KMnO4• concentrated HCl at room temperatureExtend FurtherUse your observations of the solutions formed in the previous experiments and yourunderstanding of alcohols to complete a table like the one shown below. Research the meltingand boiling points to verify your answers.Please give a step by step for this problem. Give the major organic products.