2. Use your answer to question 1 to answer questions a through d below. a. Assign oxidation numbers to all atoms/ions in your answer to questions 1. Answer:

Chemistry: An Atoms First Approach
2nd Edition
ISBN:9781305079243
Author:Steven S. Zumdahl, Susan A. Zumdahl
Publisher:Steven S. Zumdahl, Susan A. Zumdahl
Chapter20: Transition Metals And Coordination Chemistry
Section: Chapter Questions
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Can you do 2a please. I submitted another picture if my answer in question 1 isn’t clear. Thank you.
6. (a) MnU4 (aq) + C₂O4^(aq) + H(aq) → Mn(aq) + H₂O(1) + CO₂(g)
(b) Carbon is oxidized. Its oxidation number changes from +3 to +4.
(c) Manganese is reduced. Its oxidation number changes from +7 to +2.
(d) The oxidizing agent is MnO4 and the reducing agent is C₂04²¯.
7. (a) CO₂(g) + H₂O(1)→ H₂CO3(aq)
(b)
8. (a)
(b)
This is not a redox reaction. The oxidation numbers of all of the atoms remain
unchanged.
9. (a)
Cu(s) →
2 [NO3(aq) + 2 H (aq) + e→NO₂(g) + H₂O(1)]
Cu(s) +2 NO3(aq) + 4 H (aq) → Cu²+ (aq) + 2 NO₂(g) + 2 H₂O(1)
Cr₂O72(aq) + 14 H(aq) + 6 e¯→ 2 Cr³+ (aq) + 7 H₂O(1)
3 [H2O2(aq)
O₂(g) + 2 H (aq) + 2 e]
3 H₂O₂(aq) + Cr₂O7²-(aq) + 8 H*(aq) → 2 Cr³+ (aq) + 3 O₂(g) + 7 H₂O(1)
(c)
→ Cu²+ (aq) + 2 e
>
2+
2 [Mn²+ (aq) + 4H₂O(1) →MnO4 (aq) + 8 H'(aq) + 5 e]
5 [HBiO3(aq) + 5 H*(aq) + 2 e¯ → Bi³*(aq) + 3 H₂O(1)]
2+
2 Mn²+ (aq) + 5 HBiO3(aq) + 9 H*(aq) → 5 Bi³*(aq) + 2 MnO4¯(aq) + 7 H₂O(1)
2 [Cr(OH)3(s) + 5 OH(aq) → CrO4²(aq) + 4 H₂O(l) + 3 e¯]
IO3(aq) + 3 H₂O(1) + 6 e¯ → I(aq) + 6 OH(aq)
2 Cr(OH)3(s) + 4 OH¯(aq) + IO3¯(aq) → 2 CrO4²¯(aq) + 5 H₂O(1) + I (aq)
I
Transcribed Image Text:6. (a) MnU4 (aq) + C₂O4^(aq) + H(aq) → Mn(aq) + H₂O(1) + CO₂(g) (b) Carbon is oxidized. Its oxidation number changes from +3 to +4. (c) Manganese is reduced. Its oxidation number changes from +7 to +2. (d) The oxidizing agent is MnO4 and the reducing agent is C₂04²¯. 7. (a) CO₂(g) + H₂O(1)→ H₂CO3(aq) (b) 8. (a) (b) This is not a redox reaction. The oxidation numbers of all of the atoms remain unchanged. 9. (a) Cu(s) → 2 [NO3(aq) + 2 H (aq) + e→NO₂(g) + H₂O(1)] Cu(s) +2 NO3(aq) + 4 H (aq) → Cu²+ (aq) + 2 NO₂(g) + 2 H₂O(1) Cr₂O72(aq) + 14 H(aq) + 6 e¯→ 2 Cr³+ (aq) + 7 H₂O(1) 3 [H2O2(aq) O₂(g) + 2 H (aq) + 2 e] 3 H₂O₂(aq) + Cr₂O7²-(aq) + 8 H*(aq) → 2 Cr³+ (aq) + 3 O₂(g) + 7 H₂O(1) (c) → Cu²+ (aq) + 2 e > 2+ 2 [Mn²+ (aq) + 4H₂O(1) →MnO4 (aq) + 8 H'(aq) + 5 e] 5 [HBiO3(aq) + 5 H*(aq) + 2 e¯ → Bi³*(aq) + 3 H₂O(1)] 2+ 2 Mn²+ (aq) + 5 HBiO3(aq) + 9 H*(aq) → 5 Bi³*(aq) + 2 MnO4¯(aq) + 7 H₂O(1) 2 [Cr(OH)3(s) + 5 OH(aq) → CrO4²(aq) + 4 H₂O(l) + 3 e¯] IO3(aq) + 3 H₂O(1) + 6 e¯ → I(aq) + 6 OH(aq) 2 Cr(OH)3(s) + 4 OH¯(aq) + IO3¯(aq) → 2 CrO4²¯(aq) + 5 H₂O(1) + I (aq) I
Part 3: Questions
1. Complete "Section 13.3" question 8.b. on page 595 of the textbook
Answer:
D
Cr₂O₂2²cago + 14H+ (aq) + 6 e² => 2 Cr Coq) +7H ₂010
(1)
3 [H₂Ocaq -> O₂(g) + 2H+ (aq) +2e=]
3H₂O(g) +Cr 07³ (ags +8H*caqs-> 2 Cr³+ (aq) + 3 O₂(g) +7H₂0(1)
2. Use your answer to question 1 to answer questions a through d below.
a. Assign oxidation numbers to all atoms/ions in your answer to questions 1.
Answer:
Transcribed Image Text:Part 3: Questions 1. Complete "Section 13.3" question 8.b. on page 595 of the textbook Answer: D Cr₂O₂2²cago + 14H+ (aq) + 6 e² => 2 Cr Coq) +7H ₂010 (1) 3 [H₂Ocaq -> O₂(g) + 2H+ (aq) +2e=] 3H₂O(g) +Cr 07³ (ags +8H*caqs-> 2 Cr³+ (aq) + 3 O₂(g) +7H₂0(1) 2. Use your answer to question 1 to answer questions a through d below. a. Assign oxidation numbers to all atoms/ions in your answer to questions 1. Answer:
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