Up 1st rowNomenculation[Pt(NH3)4(OH)2]SO4[Pt(NH3)4][PtBr4][Pt(NH3)4][CuCl4][Co(NH3)4Brz]CI[Cr(NH3)6][Co(CN)6]K3[Fe(Ox)3]Na3[Co(NO₂)6]2nd rowIsomerism, EANCl[Co(NO₂)(SCN) (en)2][Co(NH3)4Cl2]NO₂[Co(en)2(NH3)CI]SO4[Cr(H₂O)4(NO2) CI] Br[Co(en)2(NO₂)SCN] Br[Pt(NH3)3Cl3] Br[Co(NH3)sBr]SO4M3th rowVBT, CFT, MOT,Jahn Teller[FeF6]³[Mn(CN)6][Cu(en)]2+[Pd(NH3)6]4+[Cr(H₂O)]3+[Fe(CN)6]4[Co[HzO)6]3+ 5) Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether thecoordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row).6) Draw the molecular orbital energy diagram of the coordination compound according to the Molecular OrbitalTheory (MOT) (3th row).

Orbital splitting diagram for [FeF6]3- Crystal field splitting energy for [FeF6]3- Fe(III) = d5 H.S.…

5) Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row).

5) Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row).

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Concept explainers

Organometallic Compounds of s- and p- block elements

Organometallic compounds have a minimum of one bond between a metal compound and a carbon atom. Metalloid elements such as silicon, tin, and boron form organometallic compounds which can be utilized in a few commercial chemical reactions.

Question

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1st row
Nomenculation
[Pt(NH3)4(OH)2]SO4
[Pt(NH3)4][PtBr4]
[Pt(NH3)4][CuCl4]
[Co(NH3)4Brz]CI
[Cr(NH3)6][Co(CN)6]
K3[Fe(Ox)3]
Na3[Co(NO₂)6]
2nd row
Isomerism, EAN
Cl
[Co(NO₂)(SCN) (en)2]
[Co(NH3)4Cl2]NO₂
[Co(en)2(NH3)CI]SO4
[Cr(H₂O)4(NO2) CI] Br
[Co(en)2(NO₂)SCN] Br
[Pt(NH3)3Cl3] Br
[Co(NH3)sBr]SO4
M
3th row
VBT, CFT, MOT,
Jahn Teller
[FeF6]³
[Mn(CN)6]
[Cu(en)]2+
[Pd(NH3)6]4+
[Cr(H₂O)]3+
[Fe(CN)6]4
[Co[HzO)6]3+

5) Draw the orbital splitting diagram, calculate crystal field stabilization energy and indicate whether the
coordination compound gives coloured solutions or not according to the Crystal Field Theory (CFT) (3th row).
6) Draw the molecular orbital energy diagram of the coordination compound according to the Molecular Orbital
Theory (MOT) (3th row).

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Step 1: Orbital splitting diagram and CFSE calculation for [FeF6]3-

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Step 2: Orbital splitting diagram and CFSE calculation for [Mn(CN)6]4-

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Step 3: Orbital splitting diagram and CFSE calculation for [Cu(en)3]2+

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Step 4: Orbital splitting diagram and CFSE calculation for [Pd(NH3)6]4+

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Step 5: Orbital splitting diagram and CFSE calculation for [Cr(H2O)6]3+

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Step 6: Orbital splitting diagram and CFSE calculation for [Fe(CN)6]4-

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Step 7: Orbital splitting diagram and CFSE calculation for [Co(H2O)6]3+

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Organometallic Compounds of s- and p-Block Elements

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