20.36 (a) Which of the following complexes would you expect to suffer from a Jahn-Teller distortion: [Crl], [Cr(CN)6], [CoF]³ and [Mn(ox)3]³ ? Give reasons for your answers. (b) [Et4N] 2 [NiBr4] is paramagnetic, but K₂ [PdBr4] is diamagnetic. Rationalize these observations. (c) Using a simple MO approach, explain what happens to the energies of the metal d orbitals on the formation of a o-bonded complex such as [Ni(NH3)6]2+.

Principles of Modern Chemistry
8th Edition
ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter8: Bonding In Transition Metal Compounds And Coordination Complexes
Section: Chapter Questions
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20.36 (a) Which of the following complexes would
you expect to suffer from a Jahn-Teller
distortion: [Crl], [Cr(CN)6], [CoF]³ and
[Mn(ox)3]³ ? Give reasons for your answers.
(b) [Et4N] 2 [NiBr4] is paramagnetic, but K₂ [PdBr4] is
diamagnetic. Rationalize these observations.
(c) Using a simple MO approach, explain what
happens to the energies of the metal d orbitals
on the formation of a o-bonded complex such as
[Ni(NH3)6]²+.
Transcribed Image Text:20.36 (a) Which of the following complexes would you expect to suffer from a Jahn-Teller distortion: [Crl], [Cr(CN)6], [CoF]³ and [Mn(ox)3]³ ? Give reasons for your answers. (b) [Et4N] 2 [NiBr4] is paramagnetic, but K₂ [PdBr4] is diamagnetic. Rationalize these observations. (c) Using a simple MO approach, explain what happens to the energies of the metal d orbitals on the formation of a o-bonded complex such as [Ni(NH3)6]²+.
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