Can i get help with these problems 21. Draw the mechanism of each of the following solvolysis reactions:ELOHBr(solvolysis)CIOH(solvolysis) Carbocation Rearrangement with proton transfer process:Here is an example of an Sy1 process that is accompanied by all three additional steps:H3Oʻ/MEOHÖH:OMeProtontransferProton transferNucleophilicattackLoss of leavingCarbocationgrouprearrangement- H20MeHH.Me2° carbocation3° carbocationEnergy diagram for carbocation rearrangement with proton transferLoss ofLGNucleophillicattackProtonCarbocationProtontransferrearrangementtransfercarbocationPotentialenergycarbocationMe eH-OOHOMeReaction coordinate

Interpretation- To write the mechanism of the following reactions which is given in the question .…

Answered: 21. Draw the mechanism of each of the…

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21. Draw the mechanism of each of the following solvolysis reactions: EIOH Br (solvolysis) но (solvolysis) CI

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter30: Orbitals And Organic Chemistry: Pericyclic Reactions

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Problem 14MP: Plastic photochromic sunglasses are based on the following reversible rearrangement of a dye inside...

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Question

Can i get help with these problems

21. Draw the mechanism of each of the following solvolysis reactions:
ELOH
Br
(solvolysis)
CI
OH
(solvolysis)

Carbocation Rearrangement with proton transfer process:
Here is an example of an Sy1 process that is accompanied by all three additional steps:
H3Oʻ/MEOH
ÖH
:OMe
Proton
transfer
Proton transfer
Nucleophilic
attack
Loss of leaving
Carbocation
group
rearrangement
- H20
Me
H
H.
Me
2° carbocation
3° carbocation
Energy diagram for carbocation rearrangement with proton transfer
Loss of
LG
Nucleophillic
attack
Proton
Carbocation
Proton
transfer
rearrangement
transfer
carbocation
Potential
energy
carbocation
Me e
H-O
OH
OMe
Reaction coordinate

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