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- Give the structure of compound 5 and compound 6Describe the following giving the relevant chemical equation in each case: (i) Carbylamine reaction (ii) Hoffmann’s bromamide reaction.If you were ask to prepare ethylamine, suggest two ways which you would give that would give you exclusively the desired product. Explain what is happening in each reaction steps.
- Describe and map the reaction between Potassium dichromate (K2Cr2O7) and Sodium thiosulfate as a pentahydrate (Na2S2O3·5H2O). Show all products.Propose a single synthesis method for cobalt(II) sulphate (CoSO4.7H2O) and describe in detail.A compound E C7H12O gives a crystalline precipitate with 2,4-dinitrophenylhydrazine. It gives a maximum absorption in the ultraviolet spectrum at 248 nm,( ᶓmax = 104). Suggest the possible structure(s) for compound E.
- For each of the following mixtures of reactants, give (i) a plausible chemical equation and (ii) structurefor the organometallic product, and (iii) general reason for the course of the reaction: (a)methyllithium and W(CO)6, (b) Co2(CO)8 and AlBr3.Give the expected products of lithium aluminum hydride reduction of the followingcompounds (followed by hydrolysis).(a) butyronitrile (b) N-cyclohexylacetamidestructure of product assuming acidic condition
- 3. Obtain acetophenone and acetaldehyde by reaction of glycols with periodic acid. Justify your answer with the reaction mechanism.What color do you expect for cresol purple at pH 1.0, 2.0, and 3.0?Sulfuric acid (H2SO4) is called a diprotic acid because it has two acidic protons. The pKa for the first deprotonation is -9, whereas the pKa for the second deprotonation is 2. Explain these relative acid strengths.