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The molecule PtCl 2 - is an important square planar starting material in synthetic inorganic chemistry. Using the p orbitals of Cl as the basis find the irreducible representations of the p orbitals and indicate which orbitals could possibly overlap with any of the orbitals on Pt . Assume that the pz orbitals on Cl are orientated in the same direction as the principle rotation axis, px orbitals are pointed at the Pt , and the py orbitals are orthogonal to the px orbitals. Show the characters of each orbital and identify which orbitals on Pt would match from a pure symmetry standpoint.

The molecule PtCl 2 - is an important square planar starting material in synthetic inorganic chemistry. Using the p orbitals of Cl as the basis find the irreducible representations of the p orbitals and indicate which orbitals could possibly overlap with any of the orbitals on Pt . Assume that the pz orbitals on Cl are orientated in the same direction as the principle rotation axis, px orbitals are pointed at the Pt , and the py orbitals are orthogonal to the px orbitals. Show the characters of each orbital and identify which orbitals on Pt would match from a pure symmetry standpoint.

Chemistry & Chemical Reactivity
Chemistry & Chemical Reactivity
10th Edition
ISBN:9781337399074
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter12: The Solid State
Section: Chapter Questions
Problem 19PS: Considering only the molecular orbitals formed by combinations of the 2s atomic orbitals, how many...
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The molecule PtCl 2 - is an important square planar starting material in synthetic inorganic chemistry. Using the p orbitals of Cl as the basis find the irreducible representations of the p orbitals and indicate which orbitals could possibly overlap with any of the orbitals on Pt . Assume that the pz orbitals on Cl are orientated in the same direction as the principle rotation axis, px orbitals are pointed at the Pt , and the py orbitals are orthogonal to the px orbitals. Show the characters of each orbital and identify which orbitals on Pt would match from a pure symmetry standpoint.

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