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- Give the relationships between the following pairs of structures (a), (c), (d), (e). The possible relationships are: same compound, constitutional isomer, cis-trans isomers, not isomers (different molecular formula). 2-35 Give the relation isomers, constitutional (structural) isomers, (a) CH₂CH₂CH₂CH3 and (CH3)3CH (c) (e) CH CH CH₁ and CH₂ and CH₂ CH, (d) CH3 CH₂ CH₂ CH₂-CH₂ and CH₂CH3 CH3 C=CH₂ CH3 and CH3. CH₂-CH) Calculate the ΔG°rxn using the following information. 4 HNO3(g) + 5 N2H4(l) → 7 N2(g) + 12 H2O(l) ΔG°rxn = ? ΔG°f (kJ/mol) -73.5 149.3 -237.1a. Draw and name all of the isomeric products obtainedfrom the monobromination of propane with Br2/light. If halogenation were a completely randomreaction and had an equal probability of occurring atany of the C—H bonds in a molecule, what percentage of each of these monobromo products would beexpected?b. Answer part (a) using 2-methylpropane as the starting material.
- Methyl isocyanate, CH3 -N= C = O, is used in the industrial synthesis of a type of pesticide and herbicide known as a carbamate. As a historical note, an industrial accident in Bhopal, India, in 1984 resulted in leakage of an unknown quantity of this chemical into the air. An estimated 200,000 people were exposed to its vapors, and over 2000 of these people died. Q.) Methyl isocyanate reacts with strong acids, such as sulfuric acid, to form a cation. Will this molecule undergo protonation more readily on its oxygen or nitrogen atom? In considering contributing structures to each hybrid, do not consider structures in which more than one atom has an incomplete octetNH2OH He CH3Cl CH4 Show partial/full charges when appropriatePlease write the answer clearly with the state of matter following each compound.
- for the following formulas drew 2 constitutional isomers and provide names in IUPAC for ypur drawingsFor which compound containing a heteroatom (an atom other than carbon or hydrogen) does the molecular ion have an even-numbered mass? For which does it have an odd-numbered mass? Q.) A bromoalkane with the molecular formula CnH2n11BrHow did you convert the c to k that's my only question like 25.5c to k and you got 298.65?
- In light of the nitrogen rule mentioned in Problem 12-17, what is the molecular formula of pyridine, M+=79?From the data in Figure 4-12 and Table 4-1, estimate the percentages of molecules that have their substituents in an axial orientation for the following compounds: (a) Isopropylcyclohexane (b) Fluorocyclohexane (c) Cyclohexanecarbonitrile, C6H11CNThere are four cis-trans isomers of menthol (Problem 4-45), including the one shown. Draw the other three.