3) The enzyme aldolase catalyzes the conversion of fructose-1,6-diphosphate (FDP) to dihydroxyacetone phosphate (DHAP) and glyceraldehide-3-phosphate (G3P). The reaction is A,GO(298.15 K) = 23.8 kJ mol-¹ In red blood cells the concentration of these species are [FDP] = 35 µM, [DHAP] = 130 μM, and [G3P] = 15 µM. (Remember that 1.0 μM = 1.0 x 10-6 mol L-¹. The standard state for reactions in solution can be taken as cº= 1.0 mol L-¹). Calculate A, G in a red blood cell at 25°C. Will the reaction occur spontaneously in the cell at this temperature? FDP DHAP + G3P
3) The enzyme aldolase catalyzes the conversion of fructose-1,6-diphosphate (FDP) to dihydroxyacetone phosphate (DHAP) and glyceraldehide-3-phosphate (G3P). The reaction is A,GO(298.15 K) = 23.8 kJ mol-¹ In red blood cells the concentration of these species are [FDP] = 35 µM, [DHAP] = 130 μM, and [G3P] = 15 µM. (Remember that 1.0 μM = 1.0 x 10-6 mol L-¹. The standard state for reactions in solution can be taken as cº= 1.0 mol L-¹). Calculate A, G in a red blood cell at 25°C. Will the reaction occur spontaneously in the cell at this temperature? FDP DHAP + G3P
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter16: Spontaneity Of Reaction
Section: Chapter Questions
Problem 78QAP
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Question
3) The enzyme aldolase catalyzes the conversion of fructose-1,6-diphosphate (FDP)
to dihydroxyacetone phosphate (DHAP) and glyceraldehide-3-phosphate (G3P). The
reaction is
FDP ⇄ DHAP + G3P , ∆rG
0
(298.15 K) = 23.8 kJ mol−1
In red blood cells the concentration of these species are [FDP] = 35 µM, [DHAP] =
130 µM, and [G3P] = 15 µM. (Remember that 1.0 µM = 1.0 × 10−6 mol L−1
. The
standard state for reactions in solution can be taken as c
0 = 1.0 mol L−1
).
Calculate ∆rG in a red blood cell at 25 0C. Will the reaction occur spontaneously
in the cell at this temperature?
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