3. Iron (III) oxide + carbon monoxide produce iron + carbon dioxide (Fe = 0 KJ) Fe203 (s) + 3 CO (g) → 2 Fe (s) + 3 CO2 (g)

Chemistry: Principles and Practice
3rd Edition
ISBN:9780534420123
Author:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Publisher:Daniel L. Reger, Scott R. Goode, David W. Ball, Edward Mercer
Chapter5: Thermochemistry
Section: Chapter Questions
Problem 5.84QE
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Substance
State
AHs
Substance
State
ΔΗ
-45.9
-274.5
lead(IV) oxide
lead(II) nitrate
lead(II) sulfate
ammonia
ammonium chloride
-314.4
-451.9
ammonium sulfate
s -1180.9
-919.94
barium chloride
-858.6
lithium chloride
- 408.6
-483.1
-641.5
barium nitrate
-768.2
lithium nitrate
-1473.2
magnesium chloride
magnesium oxide
magnesium sulfate
manganese(IV) oxide
manganese(II) sulfate
mercury(I) chloride
mercury(II) chloride
mercury(II) oxide (red)
barium sulfate
benzene
+82.88
-601.6
benzene
+49.080
1261.79
calcium carbonate
s -1207.6
-520.0
calcium chloride
-795.4
s -1065.3
calcium hydroxide
-983.2
-264.2
calcium nitrate
-938.2
-230.0
calcium oxide
–634.9
-90.8
calcium sulfate
carbon (diamond)
carbon (graphite)
-1434.5
methane
-74.9
nitrogen dioxide
nitrogen monoxide
dinitrogen monoxide
dinitrogen tetroxide
+1.9
+33.2
0.00
+90.29
carbon diexide
-393.5
+82.1
carbon monoxide
-110.5
+9.2
copper(II) nitrate
copper(II) oxide
-302.9
oxygen (O2)
ozone (O3)
0.00
-157.3
+142.7
copper(II) sulfate
ethane
tetraphosphorus decoxide
potassium bromide
potassium chloride
potassium hydroxide
potassium nitrate
potassium sulfate
silicon dioxide (quartz)
-771.4
s -3009.9
- 393.8
-436.49
-83.8
ethyne (acetylene)
hydrogen (H2)
hydrogen bromide
hydrogen chloride
hydrogen fluoride
hydrogen iodide
hydrogen oxide (water)
hydrogen oxide (water)
hydrogen peroxide
hydrogen peroxide
hydrogen sulfide
iodine (I2)
+228.2
0.00
- 424.58
- 36.29
-494.6
-92.3
s -1437.8
-910.7
-273.3
+26.5
-241.8
silver chloride
-127.01 ± 0.5
silver nitrate
-120.5
1.-285.8
silver sulfide
-32.59
8 -136.3
1 -187.8
sodium bromide
-361.8
sodium chloride
sodium hydroxide
s - 385.9
-425.9
-20.6
0.00
sodium nitrate
-467.9
iodine (I2)
iron(I) chloride
+62.4
sodium sulfate
1 -1387.1
8 -296.8
8 -395.7
-399.4
sulfur dioxide
iron(II) oxide
-272.0
sulfur trioxide
-824.2
iron(III) oxide
iron(II) sulfate
tin(IV) chloride
1-511.3
-928.4
zinc nitrate
-483.7
iron(II) sulfide
lead(II) oxide
AH is enthalpy of formation of the given substance from its elements. All values of AH are expressed as klimol at
25°C. Negative values of AH indicate exothermic reactions. s= solid, 1 = liquid, g = gas
-100.0
zinc oxide
-350.5
-217.3
zinc sulfate
-980.14
Transcribed Image Text:Substance State AHs Substance State ΔΗ -45.9 -274.5 lead(IV) oxide lead(II) nitrate lead(II) sulfate ammonia ammonium chloride -314.4 -451.9 ammonium sulfate s -1180.9 -919.94 barium chloride -858.6 lithium chloride - 408.6 -483.1 -641.5 barium nitrate -768.2 lithium nitrate -1473.2 magnesium chloride magnesium oxide magnesium sulfate manganese(IV) oxide manganese(II) sulfate mercury(I) chloride mercury(II) chloride mercury(II) oxide (red) barium sulfate benzene +82.88 -601.6 benzene +49.080 1261.79 calcium carbonate s -1207.6 -520.0 calcium chloride -795.4 s -1065.3 calcium hydroxide -983.2 -264.2 calcium nitrate -938.2 -230.0 calcium oxide –634.9 -90.8 calcium sulfate carbon (diamond) carbon (graphite) -1434.5 methane -74.9 nitrogen dioxide nitrogen monoxide dinitrogen monoxide dinitrogen tetroxide +1.9 +33.2 0.00 +90.29 carbon diexide -393.5 +82.1 carbon monoxide -110.5 +9.2 copper(II) nitrate copper(II) oxide -302.9 oxygen (O2) ozone (O3) 0.00 -157.3 +142.7 copper(II) sulfate ethane tetraphosphorus decoxide potassium bromide potassium chloride potassium hydroxide potassium nitrate potassium sulfate silicon dioxide (quartz) -771.4 s -3009.9 - 393.8 -436.49 -83.8 ethyne (acetylene) hydrogen (H2) hydrogen bromide hydrogen chloride hydrogen fluoride hydrogen iodide hydrogen oxide (water) hydrogen oxide (water) hydrogen peroxide hydrogen peroxide hydrogen sulfide iodine (I2) +228.2 0.00 - 424.58 - 36.29 -494.6 -92.3 s -1437.8 -910.7 -273.3 +26.5 -241.8 silver chloride -127.01 ± 0.5 silver nitrate -120.5 1.-285.8 silver sulfide -32.59 8 -136.3 1 -187.8 sodium bromide -361.8 sodium chloride sodium hydroxide s - 385.9 -425.9 -20.6 0.00 sodium nitrate -467.9 iodine (I2) iron(I) chloride +62.4 sodium sulfate 1 -1387.1 8 -296.8 8 -395.7 -399.4 sulfur dioxide iron(II) oxide -272.0 sulfur trioxide -824.2 iron(III) oxide iron(II) sulfate tin(IV) chloride 1-511.3 -928.4 zinc nitrate -483.7 iron(II) sulfide lead(II) oxide AH is enthalpy of formation of the given substance from its elements. All values of AH are expressed as klimol at 25°C. Negative values of AH indicate exothermic reactions. s= solid, 1 = liquid, g = gas -100.0 zinc oxide -350.5 -217.3 zinc sulfate -980.14
Calculate Change of Enthalpy- use Table A-14
1. Calcium carbonate breaks down into calcium oxide and carbon dioxide
CacO3 (s) → CaO (s) + CO2 (g)
2. Calcium hydroxide breaks down into calcium oxide and water (hydrogen oxide gas)
Ca(OH)2 (s) → CaO (s) + H2O (g)
3. Iron (III) oxide + carbon monoxide produce iron + carbon dioxide (Fe = 0 KJ)
Fe203 (s) + 3 CO (g) → 2 Fe (s) + 3 CO2 (g)
Transcribed Image Text:Calculate Change of Enthalpy- use Table A-14 1. Calcium carbonate breaks down into calcium oxide and carbon dioxide CacO3 (s) → CaO (s) + CO2 (g) 2. Calcium hydroxide breaks down into calcium oxide and water (hydrogen oxide gas) Ca(OH)2 (s) → CaO (s) + H2O (g) 3. Iron (III) oxide + carbon monoxide produce iron + carbon dioxide (Fe = 0 KJ) Fe203 (s) + 3 CO (g) → 2 Fe (s) + 3 CO2 (g)
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