3. Methyl orange behaves much like methyl red in the respect that it is mostly protonated at very low pH values and mostly deprotonated at high very pH values. If a solution of methyl orange at a pH of 3.53 had a [HIn] concentration of 0.0420 M and a [In'] concentration of 0.0230 M. Would would the k, of methyl orange be at this pH? Hint: see equation 2 in the lab manual O 16 x 10 O 0.548 O 5.8 x 105 O 18 x 10

Chemistry & Chemical Reactivity
9th Edition
ISBN:9781133949640
Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Publisher:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
Chapter4: Stoichiometry: Quantitative Information About Chemical Reactions
Section4.8: Stoichiometry Of Reactions In Aqueous Solution-titrations
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3. Methyl orange behaves much like methyl red in the respect that it is mostly protonated at very low pH values and mostly deprotonated at high very
pH values. If a solution of methyl orange at a pH of 3.53 had a (Hln] concentration of 0.0420 M and a [In] concentration of 0.0230 M. Would would
the k, of methyl orange be at this pH? Hint: see equation 2 in the lab manual
O 1.6 x 104
O 0.548
O 5.8 x 10-5
O 1.8 x 103
Transcribed Image Text:3. Methyl orange behaves much like methyl red in the respect that it is mostly protonated at very low pH values and mostly deprotonated at high very pH values. If a solution of methyl orange at a pH of 3.53 had a (Hln] concentration of 0.0420 M and a [In] concentration of 0.0230 M. Would would the k, of methyl orange be at this pH? Hint: see equation 2 in the lab manual O 1.6 x 104 O 0.548 O 5.8 x 10-5 O 1.8 x 103
2. You add 10.00 ml of a 0.630 M methyl red solution to a 100.00 ml volumetric flask. You then add small volumes of sodium acetate and acetic acid
solutions to adjust the pH, and then fill the 100 mL volumetric flask to the mark with deionized water. You then make a spectroscopic measurement
and obtain absorbance values of 0.253 at 520 nm and 0.079 at 420 nm. What is the concentration of [HIn] in the solution. Remember to use M;V1 =
M2V2 as the first step in the calculation process. Hint: see eq. 6 in the lab manual
A$20, = 0.367
A520, = 0.010
A420, - 0.012
A420, = 0.275
O 4.30 x 102
O 0.430
O 4.18 x 102
O 0.418
Transcribed Image Text:2. You add 10.00 ml of a 0.630 M methyl red solution to a 100.00 ml volumetric flask. You then add small volumes of sodium acetate and acetic acid solutions to adjust the pH, and then fill the 100 mL volumetric flask to the mark with deionized water. You then make a spectroscopic measurement and obtain absorbance values of 0.253 at 520 nm and 0.079 at 420 nm. What is the concentration of [HIn] in the solution. Remember to use M;V1 = M2V2 as the first step in the calculation process. Hint: see eq. 6 in the lab manual A$20, = 0.367 A520, = 0.010 A420, - 0.012 A420, = 0.275 O 4.30 x 102 O 0.430 O 4.18 x 102 O 0.418
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