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3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min 7, atm T, min T, atm 1.14 0.850 8. 0.832 1.04 0.982 0.940 3. 0.815 4 10 0.800 0.905 15 0.754 6. 0.870 20 0.728

3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min 7, atm T, min T, atm 1.14 0.850 8. 0.832 1.04 0.982 0.940 3. 0.815 4 10 0.800 0.905 15 0.754 6. 0.870 20 0.728

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min 7, atm T, min T, atm 1.14 0.850 8. 0.832 1.04 0.982 0.940 3. 0.815 4 10 0.800 0.905 15 0.754 6. 0.870 20 0.728
Transcribed Image Text:3.21. A small reaction bomb fitted with a sensitive pressure-measuring device is flushed out and then filled with pure reactant A at 1-atm pressure. The operation is carried out at 25°C, a temperature low enough that the reaction does not proceed to any appreciable extent. The temperature is then raised as rapidly as possible to 100°C by plunging the bomb into boiling water, and the readings in Table P3.21 are obtained. The stoichiometry of the reaction is 2A B, and after leaving the bomb in the bath over the weekend the contents are analyzed for A; none can be found. Find a rate equation in units of moles, liters, and minutes which will satisfactorily fit the data. Table P3.21 T, min 7, atm T, min T, atm 1.14 0.850 8. 0.832 1.04 0.982 0.940 3. 0.815 4 10 0.800 0.905 15 0.754 6. 0.870 20 0.728
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