33. The mechanism for the decomposition of NO2CI is k1 NO2C1 2 NO2 + Cl k_1 k2 NO2CI+ Cl 3 NO2+ Cl2 By making a steady-state

Principles of Modern Chemistry
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ISBN:9781305079113
Author:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Publisher:David W. Oxtoby, H. Pat Gillis, Laurie J. Butler
Chapter18: Chemical Kinetics
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33. The mechanism for the
decomposition of NO2CI is
k1
NO2 Cl 2 NO2 + Cl
k_1
k2
NO2CI+ Cl 3 NO2 + Cl2
By making a steady-state
approximation for [Cl], express
the rate of appearance of Cl2 in
terms of the concentrations of
NO2 Cl and NO2.
Transcribed Image Text:33. The mechanism for the decomposition of NO2CI is k1 NO2 Cl 2 NO2 + Cl k_1 k2 NO2CI+ Cl 3 NO2 + Cl2 By making a steady-state approximation for [Cl], express the rate of appearance of Cl2 in terms of the concentrations of NO2 Cl and NO2.
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