33. What are the expected products from the reaction shown? o (A) (B) (C) (D) -O-CH₂CH₂CH₂OH HBr (excess) -Br+ BrCH₂CH₂CH₂OH -Br+ BrCH₂CH₂CH₂Br -OH + BrCH₂CH₂CH₂Br o -0-CH₂CH₂CH₂OH
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- What are the products and reactants of the following: a) Isobutylmagnesium bromide + H2O -> Ab) sec-butyl bromide + Li/CuI -> B c) B + CH3CH2Br -> CPredict the major products, and if reaction is not feasible then write NR.Which of the following is the correct step of protonation of tran-2-butene? A B C D
- predict the products: XCL2+ E3PO4 --->predict the stating materials, reagents, or products of the followinf reactionsArrange the following compounds in the increasing order of reactivity towards Conc.HNO3 & Conc.H₂SO4 1. Benzene 2. Chlorobenzene 3. phenol 4. Toluene 5. Nitrobenzene A 1.2.3.4.5 (B) 5.1,243 5.1.4.2.3 D 5.2.1.4.3
- Provide a reasonable arrow-pushing mechanism for Reaction 5b, and explain the the stereochemical outcome. 5d belowOrganotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides. One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(CzHs)3). 3SnCl4 + 4Al(C2H5)3 → 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.160 L of SnCl4 (d= 2.226 g/mL) was treated with 0.346 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). What is the theoretical yield in this experiment (mass of tetraethylstannane, Sn(C2H5)4)? If 0.257L of tetraethylstannane (d= 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?Organotin compounds play a significant role in diverse industrial applications. They have been used as plastic stabilizers and as pesticides or fungicides.One method used to prepare simple tetraalkylstannanes is the controlled direct reaction of liquid tin(IV) chloride with highly reactive trialkylaluminum compounds, such as liquid triethylaluminum (Al(C2H5)3). 3SnCl4 + 4Al(C2H5)3 3Sn(C2H5)4 + 4AlCl3 In one experiment, 0.230 L of SnCl4 (d = 2.226 g/mL) was treated with 0.396 L of triethylaluminum (Al(C2H5)3); d = 0.835 g/mL). If 0.335 L of tetraethylstannane (d = 1.187 g/mL) were actually isolated in this experiment, what was the percent yield?
- Suggest an explanation for the fact that the order of reactivity of the halides toward n-butylbrosylate in acetone is Cl” > Br” > I~ when (C4H9)4N* is the cation of the halide salt butI” > Br” > Cl” when Li’ is the cation35.) What would be the preferred product for each of the following reactions ( hint : ether formation , ether-cleavage, diene formation , 1,2/1,4-addition, epoxidation and Diels-Alder cycloaddition?An inexperienced graduate student treated dec-5-ene with borane in THF, placed the flask in a refrigerator, and left for aparty. When he returned from the party, he discovered that the refrigerator was broken and that it had gotten quite warminside. Although all the THF had evaporated from the flask, he treated the residue with basic hydrogen peroxide. Tohis surprise, he recovered a fair yield of decan-1-ol. Use a mechanism to show how this reaction might have occurred.(Hint: The addition of BH3 is reversible.)