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4. Consider the reaction: 2 A + B → products The tentative rate law is: rate k [A]* [B]" 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M Use integrated rate equations to determine The order wrt [A]. а. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10 1.000 x 10 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10* 0.883 x 10* 10 min 0.607 x 10 0.779 x 10* 20 min 0.368 x 10 0.607 x 10

4. Consider the reaction: 2 A + B → products The tentative rate law is: rate k [A]* [B]" 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M Use integrated rate equations to determine The order wrt [A]. а. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10 1.000 x 10 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10* 0.883 x 10* 10 min 0.607 x 10 0.779 x 10* 20 min 0.368 x 10 0.607 x 10

Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
8th Edition
ISBN:9781305079373
Author:William L. Masterton, Cecile N. Hurley
Publisher:William L. Masterton, Cecile N. Hurley
Chapter11: Rate Of Reaction
Section: Chapter Questions
Problem 30QAP
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4. Consider the reaction: 2 A + B → products The tentative rate law is: rate = k [A]* [B] 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. Use integrated rate equations to determine The order wrt [A]. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M %3D %3D a. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10° 1.000 x 10° 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10 0.883 x 10° 10 min 0.607 x 10° 0.779 x 10 20 min 0.368 x 10 0.607 x 10°
Transcribed Image Text:4. Consider the reaction: 2 A + B → products The tentative rate law is: rate = k [A]* [B] 2 experiments were performed. For Exp. 2: [A]o = 1.000 x 10° M; [B]o = 0.50 M The conc of A was tracked. This is an isolation experiment which simplifies the determination of the rate law. Use integrated rate equations to determine The order wrt [A]. For Exp. 1: [A]o = 1.000 x 10³ M; [B]o = 1.00 M %3D %3D a. Exp.1 Exp. 2 Time [A] (M) [A] (M) O min 1.000 x 10° 1.000 x 10° 0.951 x 10 0.975 x 10 Compare the rates of rx for Exp. 1 & 2 to determine the order of rx wrt [B]. b. 1 min 5 min 0.779 x 10 0.883 x 10° 10 min 0.607 x 10° 0.779 x 10 20 min 0.368 x 10 0.607 x 10°
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