4. Explain the stereochemistry of the following reactions shown below of the products B &C CR). 1. SO2CI /pyridine Но н 1. SOCIzlether 2. CH3O Na/CH3OH 2. CH3O Na/CH3OH (R)- (S)- (S)- A

Organic Chemistry: A Guided Inquiry
2nd Edition
ISBN:9780618974122
Author:Andrei Straumanis
Publisher:Andrei Straumanis
Chapter8: Addition Via Carbocation
Section: Chapter Questions
Problem 6CTQ
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4. Explain the stereochemistry of the following reactions shown below of the
products B & C (OR).
1.
SO2CI /pyridine
HO H
1.SOCI/ether
2. CH30 Na/CH,OH
2. CH;O Na/CH,OH
(R)-
(S)-
(S)-
A
B
5. Provide a detailed mechanism for the following reaction. Draw the structures of
the products. Explain your answer S).
HI
A
B
6. Methylcyclopentanol on treatment with HBr gives 1-bromo-1-methylcyclopentane
as a major product. Show a detailed mechanism to explain your answer .
S).
CH3
H3C
Br
HBr
но-
-H2O
2-methylcyclopentanol
1-bromo-1-methylcyclopentane
CS Scanned with CamScanner
Transcribed Image Text:4. Explain the stereochemistry of the following reactions shown below of the products B & C (OR). 1. SO2CI /pyridine HO H 1.SOCI/ether 2. CH30 Na/CH,OH 2. CH;O Na/CH,OH (R)- (S)- (S)- A B 5. Provide a detailed mechanism for the following reaction. Draw the structures of the products. Explain your answer S). HI A B 6. Methylcyclopentanol on treatment with HBr gives 1-bromo-1-methylcyclopentane as a major product. Show a detailed mechanism to explain your answer . S). CH3 H3C Br HBr но- -H2O 2-methylcyclopentanol 1-bromo-1-methylcyclopentane CS Scanned with CamScanner
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