4. Various mixtures of ethanol and ethyl acetate were heated to different temperature at a pressure of 101325 Pa and the following compositions of the liquid and condensed vapour determined. T/(C 77.2 76.7 75.0 72.6 71.8 71.6 72.0 72.8 74.2 76.4 77.7 78.3 XEthanol 0.000 0.025 0.100 0.240 0.360 0.462 0.563 0.710 0.883 0.942 0.982 1.000 VEthanol 0.000 0.070 0.164 0.295 0.398 0.462 0.507 0.600 0.735 0.880 0.965 1.000 a) Use the data to construct a labelled temperature-composition phase diagram. Explain the form of the phase diagram in terms of the interactions between the two components.

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4. Various mixtures of ethanol and ethyl acetate were heated to different temperature at a
pressure of 101325 Pa and the following compositions of the liquid and condensed vapour
determined.
T/(C 77.2
76.7
75.0
72.6
71.8
71.6
72.0
72.8
74.2
76.4
77.7
78.3
0.000 0.025 0.100 0.240 0.360 0.462 0.563 0.710 0.883 0.942 0.982 1.000
XEthanol
YEthanol
0.000 0.070 0.164 0.295 0.398 0.462 0.507 0.600 0.735 0.880 0.965 1.000
a) Use the data to construct a labelled temperature-composition phase diagram. Explain
the form of the phase diagram in terms of the interactions between the two components.
b) A solution in which the mole fraction of ethanol was 0.8 was distilled in an open boiler
at a pressure of 101325 Pa. Use your phase diagram to determine the temperature at
which the mixture boiled and the mole fraction of ethanol in the first vapour to be
produced. What is the composition of the last vapour to evaporate?
c) A solution in which the mole fraction of ethanol was 0.2 was distilled in a fractional
distillation column at a pressure of 101325 Pa. Use your phase diagram to determine the
mole fraction of ethanol in the uppermost plate of the column.
Transcribed Image Text:4. Various mixtures of ethanol and ethyl acetate were heated to different temperature at a pressure of 101325 Pa and the following compositions of the liquid and condensed vapour determined. T/(C 77.2 76.7 75.0 72.6 71.8 71.6 72.0 72.8 74.2 76.4 77.7 78.3 0.000 0.025 0.100 0.240 0.360 0.462 0.563 0.710 0.883 0.942 0.982 1.000 XEthanol YEthanol 0.000 0.070 0.164 0.295 0.398 0.462 0.507 0.600 0.735 0.880 0.965 1.000 a) Use the data to construct a labelled temperature-composition phase diagram. Explain the form of the phase diagram in terms of the interactions between the two components. b) A solution in which the mole fraction of ethanol was 0.8 was distilled in an open boiler at a pressure of 101325 Pa. Use your phase diagram to determine the temperature at which the mixture boiled and the mole fraction of ethanol in the first vapour to be produced. What is the composition of the last vapour to evaporate? c) A solution in which the mole fraction of ethanol was 0.2 was distilled in a fractional distillation column at a pressure of 101325 Pa. Use your phase diagram to determine the mole fraction of ethanol in the uppermost plate of the column.
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